An undulation theory for condensation in open end slit pores: critical hysteresis temperature & critical hysteresis pore size

被引：24

作者：

Fan, Chunyan ^{[1
]}

Zeng, Yonghong ^{[2
]}

Do, D. D. ^{[2
]}

Nicholson, D. ^{[2
]}

机构：

[1] Curtin Univ, Dept Chem Engn, Bentley, WA 6845, Australia

[2] Univ Queensland, Sch Chem Engn, St Lucia, Qld 4072, Australia

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2014年 / 16卷 / 24期

基金：

澳大利亚研究理事会;

关键词：

CAPILLARY CONDENSATION; COMPUTER-SIMULATION; ADSORPTION; FLUIDS; MODEL; EQUILIBRIA; ISOTHERMS;

D O I：

10.1039/c4cp00848k

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new theory of condensation in an open end slit pore, based on the concept of temperature dependent undulation, at the interface separating the adsorbed phase and the gas-like region, is presented. The theory, describes, for the first time, the microscopic origin of the critical hysteresis temperature and the critical hysteresis pore size, properties which are not accessible to any classical theories.

引用

页码：12362 / 12373

页数：12

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