Electrodeposition of Gold in an Amide-Type Ionic Liquid

被引：16

作者：

Katayama, Yasushi ^{[1
]}

Endo, Tomoyuki ^{[1
]}

Miura, Takashi ^{[1
]}

Toshima, Kazunobu ^{[1
]}

机构：

[1] Keio Univ, Fac Sci & Technol, Dept Appl Chem, Yokohama, Kanagawa 2238522, Japan

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2014年 / 161卷 / 03期

关键词：

ELECTROCHEMICAL PREPARATION; ANODIC BEHAVIOR; GLASSY-CARBON; CHLORIDE-ION; MOLTEN-SALT; NANOPARTICLES; DEPOSITION; COMPLEXES; PALLADIUM; REDUCTION;

D O I：

10.1149/2.010403jes

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Electrode reactions of monovalent and trivalent bromoaurates, [(AuBr2)-Br-I] and [(AuBr4)-Br-III](-), have been investigated in an amide-type ionic liquid, 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide. [(AuBr4)-Br-III] could be reduced to metallic Au via an intermediate species, [(AuBr2)-B-I](-), which was stable in the ionic liquid. [(AuBr2)-B-I](-) could be prepared by a proportionation reaction of [(AuBr4)-B-III](-) and Au in the ionic liquid. Although metallic Au was deposited on a glassy carbon substrate at -1.5 V vs. Ag/Ag(I), Au nano-particles with an average diameter of (2.6 +/- 0.6) nm were formed and dispersed in the ionic liquid by potentiostatic cathodic reduction on a glassy carbon electrode at -2.5 V vs. Ag/Ag(I). (C) 2013 The Electrochemical Society. All rights reserved.

引用

收藏

页码：D87 / D91

页数：5

相关论文

共 45 条

[1] Voltammetric studies of gold, protons, and [HCl2]- in ionic liquids [J].

Aldous, Leigh ;

Silvester, Debbie S. ;

Pitner, William R. ;

Compton, Richard G. ;

Lagunas, M. Cristina ;

Hardacre, Christopher .

JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (24) :8496-8503

[2] Electrochemical studies of gold and chloride in ionic liquids [J].

Aldous, Leigh ;

Silvester, Debbie S. ;

Villagran, Constanza ;

Pitner, William R. ;

Compton, Richard G. ;

Lagunas, M. Cristina ;

Hardacre, Christopher .

NEW JOURNAL OF CHEMISTRY, 2006, 30 (11) :1576-1583

[3] Role of nanoparticle surface charge in surface-enhanced Raman scattering [J].

Alvarez-Puebla, RA ;

Arceo, E ;

Goulet, PJG ;

Garrido, JJ ;

Aroca, RF .

JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (09) :3787-3792

[4] Electrodeposition of palladium in a hydrophobic 1-n-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl) imide room-temperature ionic liquid [J].

Bando, Yuri ;

Katayama, Yasushi ;

Miura, Takashi .

ELECTROCHIMICA ACTA, 2007, 53 (01) :87-91

[5] Anodic behavior of gold in 1-butyl-3-methylimidazolium methanesulfonate ionic liquid with chloride anion [J].

Billy, Emmanuel ;

Chainet, Eric ;

Tedjar, Farouk .

ELECTROCHIMICA ACTA, 2011, 56 (28) :10340-10346

[6] ELECTROCHEMICAL STUDIES OF THE CATHODE PROCESS IN PURE MOLTEN MAGNESIUM-CHLORIDE [J].

BORRESEN, B ;

HAARBERG, GM ;

TUNOLD, R ;

WALLEVIK, O .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1993, 140 (06) :L99-L100

[7] Electrodeposition of Au from [EMIm][TFSA] room-temperature ionic liquid: An electrochemical and Surface-Enhanced Raman Spectroscopy study [J].

Bozzini, Benedetto ;

Tondo, Elisabetta ;

Bund, Andreas ;

Ispas, Adriana ;

Mele, Claudio .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2011, 651 (01) :1-11

[8] Plasma electrochemistry in ionic liquids: deposition of copper nanoparticles [J].

Brettholle, M. ;

Hoefft, O. ;

Klarhoefer, L. ;

Mathes, S. ;

Maus-Friedrichs, W. ;

El Abedin, S. Zein ;

Krischok, S. ;

Janek, J. ;

Endres, F. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2010, 12 (08) :1750-1755

[9]

Christie I. R., 1994, GOLD BULL, V24, P12

[10] Electrodeposition of gold thin films from 1-butyl-1-methylpyrrolidinium dicyanamide Au3+ solutions [J].

de Sa, A. I. ;

Eugenio, S. ;

Quaresma, S. ;

Rangel, C. M. ;

Vilar, R. .

THIN SOLID FILMS, 2011, 519 (19) :6278-6283

← 1 2 3 4 5 →