Lewis-acid-promoted catalytic cascade conversion of glycerol to lactic acid by polyoxometalates

被引：45

作者：

Tao, Meilin ^{[1
]}

Zhang, Dan ^{[1
]}

Deng, Xi ^{[1
]}

Li, Xiangyu ^{[2
]}

Shi, Junyou ^{[2
]}

Wang, Xiaohong ^{[1
]}

机构：

[1] NE Normal Univ, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Peoples R China

[2] Beihua Univ, Wood Mat Sci & Engn Key Lab Jilin Prov, Beihua 132013, Jilin, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 16期

基金：

中国国家自然科学基金;

关键词：

SELECTIVE OXIDATION; HETEROPOLYACIDS; ESTERIFICATION; PLATFORM;

D O I：

10.1039/c5cc10262f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The polyoxometalates AlPMo12O40 and CrPMo12O40 show high activity and reusablility for cascade conversion of glycerol directly to lactic acid under mild conditions without the addition of base, and can be reused more than 12 times with 90.5% selectivity at 93.7% conversion. AlPMo12O40 is tolerant to crude glycerol from biodiesel production.

引用

页码：3332 / 3335

页数：4

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