Synthesis and characterization of heterodinuclear complexes pentacarbonyl[(dimethylaminomethyl)ferrocene] molybdenum and pentacarbonyl[(dimethylaminomethyl)ferrocene]tungsten

被引：3
|
作者：
Pavlík, I [1 ]
Pavlista, M
Jacob, K
Pietzsch, C
Lébl, T
Vinklárek, J
机构：
[1] Univ Pardubice, Fac Chem Technol, Dept Gen & Inorgan Chem, CZ-53210 Pardubice, Czech Republic
[2] Univ Halle Wittenberg, Dept Inorgan Chem, D-06099 Halle, Germany
[3] Min Acad Tech Univ, Dept Appl Phys, D-09596 Freiburg, Germany
来源：
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS | 2000年 / 65卷 / 01期
关键词：
(dimethylaminomethyl)ferrocene; donor-acceptor complexes; molybdenum; tungsten; NMR spectroscopy; UV-VIS spectroscopy; IR spectroscopy; Mossbauer spectroscopy; metallocenes; ferrocenes; carbonyl complexes;
D O I：
10.1135/cccc20000023
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Dimethylaminomethyl)ferrocene (HFcR, R = CH2NMe2) reacts with Mo(CO)(6) and W(CO)(6) under substitution of one CO group and formation of the donor-acceptor complexes of the formula HFcRM(CO)(5) (M = Mo, W). These yellow microcrystalline derivatives were characterized by mass, UV-VIS, IR, NMR and Mossbauer spectroscopy.
引用
收藏
页码：23 / 34
页数：12
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