Synthesis and characterization of heterodinuclear complexes pentacarbonyl[(dimethylaminomethyl)ferrocene] molybdenum and pentacarbonyl[(dimethylaminomethyl)ferrocene]tungsten

被引：3

作者：

Pavlík, I ^{[1
]}

Pavlista, M

Jacob, K

Pietzsch, C

Lébl, T

Vinklárek, J

机构：

[1] Univ Pardubice, Fac Chem Technol, Dept Gen & Inorgan Chem, CZ-53210 Pardubice, Czech Republic

[2] Univ Halle Wittenberg, Dept Inorgan Chem, D-06099 Halle, Germany

[3] Min Acad Tech Univ, Dept Appl Phys, D-09596 Freiburg, Germany

来源：

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS | 2000年 / 65卷 / 01期

关键词：

(dimethylaminomethyl)ferrocene; donor-acceptor complexes; molybdenum; tungsten; NMR spectroscopy; UV-VIS spectroscopy; IR spectroscopy; Mossbauer spectroscopy; metallocenes; ferrocenes; carbonyl complexes;

D O I：

10.1135/cccc20000023

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Dimethylaminomethyl)ferrocene (HFcR, R = CH2NMe2) reacts with Mo(CO)(6) and W(CO)(6) under substitution of one CO group and formation of the donor-acceptor complexes of the formula HFcRM(CO)(5) (M = Mo, W). These yellow microcrystalline derivatives were characterized by mass, UV-VIS, IR, NMR and Mossbauer spectroscopy.

引用

页码：23 / 34

页数：12

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