Structure, optical, and radiation shielding properties of PVA-BaTiO3 nanocomposite films: An experimental investigation

被引:98
作者
Issa, Shams AM. [1 ,2 ]
Zakaly, Hesham M. H. [2 ,3 ]
Pyshkina, Mariia [3 ]
Mostafa, Mostafa Y. A. [3 ,4 ]
Rashad, M. [1 ,5 ]
Soliman, T. S. [6 ,7 ]
机构
[1] Univ Tabuk, Fac Sci, Phys Dept, Tabuk 71451, Saudi Arabia
[2] Al Azhar Univ, Assuit Branch, Fac Sci, Assiut 71524, Egypt
[3] Ural Fed Univ, Inst Phys & Technol, Ekaterinburg 620002, Russia
[4] Minia Univ, Dept Phys, Fac Sci, El Minia, Egypt
[5] Assiut Univ, Fac Sci, Phys Dept, Assiut 71516, Egypt
[6] Ural Fed Univ, Inst Nat Sci & Math, Ekaterinburg 620000, Russia
[7] Benha Univ, Fac Sci, Phys Dept, Banha 13518, Egypt
关键词
PVA-BaTiO3; nanoparticles; Shielding properties; Structure; FLUKA code; Optical properties; MASS ATTENUATION COEFFICIENTS; EFFECTIVE ATOMIC NUMBERS; ELECTRICAL-PROPERTIES; POLYVINYL-ALCOHOL; BORON-CARBIDE; COMPOSITE; CONDUCTIVITY; PARAMETERS; DENSITIES; NITRIDE;
D O I
10.1016/j.radphyschem.2020.109281
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Developing different types of radiation shielding with certain specifications according to the type of radiation and method of application is essential. In this work, the radiation shielding, optical and structural features of PVA films containing BaTiO3 nanoparticles are investigated. The radiation shielding properties were measured experimentally with real gamma sources (Ba-133, Eu-152, and Cs-137). The efficiency calibration and spectrum analysis were performed with the Spectra Line Ultimate Gamma Lab packet program. Moreover, the results were compared with the FLUKA Monte Carlo code. Before radiation attenuation measurements, the prepared films were characterized via X-ray diffraction (XRD). The structure of the BaTiO3 nanoparticles in the polymer matrix was studied with a scanning electron microscope (SEM, Merlin, Carl-Zeiss, LE0982). In addition, the optical properties of the polymer films were studied and presented. As the BaTiO3 content increases in the polymer matrix, transmission decreases and reflectance increases. Equally, as the BaTiO3 content increases, the value of a increases. For the shielding properties, the mass attenuation coefficient (mu(m)) increases as the BaTiO3 content increases from 0.65 to 3.57 wt%. There is a strong agreement between experimental results and the values obtained from the FLUKA Monte Carlo code.
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页数:13
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