Conjugated Polyelectrolyte/Graphene Hetero-Bilayer Nanocomposites Exhibit Temperature Switchable Type of Conductivity

被引：14

作者：

Brus, Viktor V. ^{[1
]}

Gluba, Marc A. ^{[1
]}

Mai, Cheng-Kang ^{[2
]}

Fronk, Stephanie L. ^{[2
]}

Rappich, Joerg ^{[1
]}

Nickel, Norbert H. ^{[1
]}

Bazan, Guillermo C. ^{[2
]}

机构：

[1] Helmholtz Zentrum Berlin Mat & Energie GmbH, Inst Silizium Photovolta, D-12489 Berlin, Germany

[2] Univ Calif Santa Barbara, Ctr Polymers & Organ Solids, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

来源：

ADVANCED ELECTRONIC MATERIALS | 2017年 / 3卷 / 02期

基金：

美国国家科学基金会;

关键词：

RAMAN-SPECTROSCOPY; HIGH-EFFICIENCY; WORK FUNCTION; DIRAC POINT; GRAPHENE; FUNCTIONALIZATION; METAL;

D O I：

10.1002/aelm.201600515

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The majority of charge carriers in conjugated polyelectrolyte (CPE)-PyrBIm(4)/graphene hetero-bilayers can be dynamically changed from electrons to holes, and vice versa, within a temperature range of 60 degrees C. Doping mechanisms under consideration include charge transfer from structural units in the CPE-PyrBIm(4) backbone and/or field-effect doping from adjacent ionic functionalities. A new concept of the graphene/CPE/Au thermobarristor is proposed and practically realized.

引用

页数：7

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