Ionic liquids in a poly ethylene oxide cross-linked gel polymer as an electrolyte for electrical double layer capacitor

被引:84
作者
Chaudoy, V. [1 ]
Van, F. Tran [1 ]
Deschamps, M. [2 ]
Ghamouss, F. [1 ]
机构
[1] Univ Tours, Lab Phys Chimie Mat & Elect l Eergie, PCM2E, EA 6299, Parc Grandmont, F-37200 Tours, France
[2] CEMHTI CNRS UPR3079, 1D Ave Rech Scientifique, F-45071 Orleans 2, France
关键词
Cross-linked polymer electrolyte; Gel polymer electrolyte; Room temperature ionic liquid; P13FSI; EDLC; SOLID-STATE SUPERCAPACITOR; CARBON-CARBON SUPERCAPACITORS; ELECTROCHEMICAL CAPACITORS; LITHIUM BATTERIES; TEMPERATURE; STORAGE; ENERGY; PERFORMANCES; MIXTURES; SOLVENTS;
D O I
10.1016/j.jpowsour.2016.12.097
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the present work, we developed a gel polymer electrolyte via the incorporation of a room temperature ionic liquid into a cross-linked polymer matrix. The cross-linked gel electrolyte was prepared using a free radical polymerization of methacrylate and dimethacrylate oligomers dissolved in 1-propyl-1methylpyrrolidinium bis(fluorosulfonyl)imide. Combining the advantages of the ionic liquids and of conventional polymers, the cross-linked gel polymer electrolyte was used both as a separator and as an electrolyte for a leakage-free and non-flammable EDLC supercapacitor. The quasi-all solid-state super capacitors showed rather good capacitance, power and energy densities by comparison to a liquid electrolyte-based EDLC. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:872 / 878
页数:7
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