Synthesis, characterization, antibacterial and catalytic activity of a nanopolymer supported copper(II) complex as a highly active and recyclable catalyst for the formamidation of arylboronic acids under aerobic conditions

被引:36
作者
Nasrollahzadeh, Mahmoud [1 ]
Zahraei, Ali [2 ]
Ehsani, Ali [1 ]
Khalaj, Mehdi [3 ]
机构
[1] Univ Qom, Fac Sci, Dept Chem, Qom 37185369, Iran
[2] Islamic Azad Univ, Qom Branch, Young Researchers & Elite Club, Qom, Iran
[3] Islamic Azad Univ, Buinzahra Branch, Dept Chem, Buinzahra, Qazvin, Iran
关键词
PROMOTED GREEN APPROACH; TETRAZOLE COMPLEXES; ROOM-TEMPERATURE; N-FORMYLATION; WATER; SULFONAMIDES; AMINES; ELECTROLUMINESCENCE; ARYLATION; EFFICIENT;
D O I
10.1039/c4ra02052a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This paper reports on the synthesis and use of a nanopolymer supported copper(II) complex, as a separable catalyst for the formamidation of arylboronic acids under aerobic conditions. The catalyst was characterized using powder XRD, SEM, EDS, TGA-DTG and FT-IR spectroscopy. This method has the advantages of high yields, elimination of homogeneous catalysts, simple methodology and easy work up. Catalytic efficiency remains unaltered even after several repeated cycles. The synthesized catalyst is found to be more highly toxic towards Gram-positive bacteria than Gram-negative bacteria.
引用
收藏
页码:20351 / 20357
页数:7
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