Kinetics of flow-induced coalescence and form relaxation in polymer blends as studied by rheo small angle light scattering

被引：0

作者：

Börschig, C ^{[1
]}

Arends, P ^{[1
]}

Gronski, W ^{[1
]}

Friedrich, C ^{[1
]}

机构：

[1] Univ Freiburg, Inst Makromol Chem, D-79104 Freiburg, Germany

来源：

MACROMOLECULAR SYMPOSIA | 2000年 / 149卷

关键词：

D O I：

10.1002/1521-3900(200001)149:1<137::AID-MASY137>3.0.CO;2-0

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The kinetics of flow-induced coalescence in PS/PMMA (polystyrene/polymethylmethacrylate) blends containing 1 wt% and 5 wt% PMMA was measured by rheo small angle light scattering under conditions of non-deformed droplets. The results are in agreement with a coalescence model which includes binary hydrodynamic interactions. Under conditions where droplet deformation occurs, coalescence is suppressed and the interfacial tension was determined from the form relaxation time on the basis of the Palierne model.

引用

页码：137 / 143

页数：7

共 50 条

[31] KINETICS OF PRECIPITATION OF CELLULOSE XANTHATE FROM A CONCENTRATED SOLUTION AS STUDIED BY SMALL-ANGLE SCATTERING OF POLARIZED-LIGHT [J].

PRIMKULO.MT ;

POKROVSK.VN ;

SERKOV, AT ;

DOLGOVA, IF .

VYSOKOMOLEKULYARNYE SOEDINENIYA SECTION B, 1972, 14 (06) :455-&

[32] THEORY ON THE SMALL ANGLE SCATTERING OF LIGHT TO DETERMINE THE SHAPE, SIZE AND ORIENTATION OF HIGH POLYMER MOLECULES IN FLOW [J].

NAKAGAKI, M .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1960, 33 (04) :476-481

[33] Breakdown kinetics of fluorocarbon micelles studied by stopped-flow small-angle X-ray scattering [J].

Eastoe, J ;

Dalton, JS ;

Downer, A ;

Jones, G ;

Clarke, D .

LANGMUIR, 1998, 14 (07) :1937-1939

[34] Breakdown kinetics of fluorocarbon micelles studied by stopped-flow small-angle X-ray scattering [J].

School of Chemistry, University of Bristol, Bristol BS8 1TS, United Kingdom ;

不详 .

Langmuir, 7 (1937-1939)

[35] Polymer-induced transient networks in water-in-oil microemulsions studied by small-angle x-ray and dynamic light scattering [J].

Blochowicz, T. ;

Goegelein, C. ;

Spehr, T. ;

Mueller, M. ;

Stuehn, B. .

PHYSICAL REVIEW E, 2007, 76 (04)

[36] Flow-induced structural transitions and instability formation in self-assembled micelles revealed by flow-small angle neutron scattering [J].

McCauley, Patrick J. ;

Kumar, Satish ;

Calabrese, Michelle A. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2023, 79 :C4-C4

[37] Phase formation kinetics in a glass ceramic studied by small-angle scattering of X-rays and neutrons and by visible-light scattering [J].

Lembke, U. ;

Bruckner, R. ;

Kranold, R. ;

Hoche, Th. .

Journal of Applied Crystallography, 1997, 30 (pt 6)

[38] Phase formation kinetics in a glass ceramic studied by small-angle scattering of X-rays and neutrons and by visible-light scattering [J].

Lembke, U ;

Bruckner, R ;

Kranold, R ;

Hoche, T .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1997, 30 :1056-1064

[39] SMALL-ANGLE LIGHT-SCATTERING OF POLYMER LIQUID-CRYSTALS UNDER SHEAR-FLOW [J].

TAKEBE, T ;

HASHIMOTO, T ;

ERNST, B ;

NAVARD, P ;

STEIN, RS .

JOURNAL OF CHEMICAL PHYSICS, 1990, 92 (02) :1386-1396

[40] Shear-induced structural transition in a lyotropic lamellar phase studied using small angle neutron and light scattering [J].

Kato, T ;

Miyazaki, K ;

Kawabata, Y ;

Komura, S ;

Fujii, M ;

Imai, M .

JOURNAL OF PHYSICS-CONDENSED MATTER, 2005, 17 (31) :S2923-S2928

← 1 2 3 4 5 →