Novel aziridination of olefins:: direct synthesis from sulfonamides using t-BuOI

被引：71

作者：

Minakata, Satoshi ^{[1
]}

Morino, Yoshinobu ^{[1
]}

Oderaotoshi, Yoji ^{[1
]}

Komatsu, Mitsuo ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 31期

关键词：

D O I：

10.1039/b606499j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

tert-Butyl hypoiodite (t-BuOI) was found to be a powerful reagent for synthesis of aziridines from olefins and sulfonamides. The aziridination of olefins was achieved by using sulfonamides with t-BuOI. Our preliminary findings represent the example of metal-free aziridination of olefins with readily accessible sulfonamides as a nitrogen source.

引用

页码：3337 / 3339

页数：3

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