Structure and properties of TiSiN/Cu multilayer coatings deposited on Ti6Al4V prepared by arc ion plating

被引:23
作者
Bai, Xuebing [1 ,3 ]
Li, Jinlong [1 ,2 ]
Zhu, Lihui [3 ]
机构
[1] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Zhejiang Key Lab Marine Mat & Protect Technol, Key Lab Marine Mat & Related Technol, Ningbo 315201, Zhejiang, Peoples R China
[2] Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China
[3] Shanghai Univ, Sch Mat Sci & Engn, Shanghai 200072, Peoples R China
基金
中国国家自然科学基金;
关键词
TiSiN/Cu multilayer coating; Arc ion plating; Structure; Anti-fouling; Anti-bacterial; X-RAY PHOTOELECTRON; TI-SI-N; ANTIBACTERIAL PROPERTIES; MECHANICAL-PROPERTIES; TRIBOLOGICAL PROPERTIES; CU CONTENT; COPPER; CORROSION; MICROSTRUCTURE; CHEMISTRY;
D O I
10.1016/j.surfcoat.2019.05.013
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The TiSiN/Cu nano-multilayer coatings were deposited on Ti6Al4V substrate by multi-arc ion plating. The distribution and diffusion of Cu were controlled by the designed thickness of Cu layer and TiSiN barrier layer. Anti-bacterial behaviors and anti-fouling properties of TiSiN/Cu multilayer coatings were investigated. The TiSiN/Cu multilayer coating consists of nano-crystalline TiN and amorphous Si3N4. The metallic copper presents as nanosize clusters. When the copper layer thickness is 97.10 nm, the TiSiN/Cu coating with the maximum hardness 40.39 +/- 0.77 GPa has the best antifouling behavior with the reduction rate of 79.36%, 66.21% and 41.37% for the P. triceratium, N. closterium and chlorella, respectively. Meanwhile, the TiSiN/Cu multilayer coatings have an excellent anti-bacterial behavior against Escherichia coli and Bacillus sp.
引用
收藏
页码:16 / 25
页数:10
相关论文
共 40 条
[1]   Marine paints: The particular case of antifouling paints [J].
Almeida, Elisabete ;
Diamantino, Teresa C. ;
de Sousa, Orlando .
PROGRESS IN ORGANIC COATINGS, 2007, 59 (01) :2-20
[2]   Synthesis, characterization, and antifouling potential of functionalized copper nanoparticles [J].
Anyaogu, Kelechi C. ;
Fedorov, Andrei V. ;
Neckers, Douglas C. .
LANGMUIR, 2008, 24 (08) :4340-4346
[3]   Effect of Cu content on microstructure, mechanical and anti-fouling properties of TiSiN-Cu coating deposited by multi-arc ion plating [J].
Bai, Xuebing ;
Li, Jinlong ;
Zhu, Lihui ;
Wang, Liping .
APPLIED SURFACE SCIENCE, 2018, 427 :444-451
[4]   SURFACE-CHEMISTRY OF SILICON-NITRIDE POWDERS - ELECTROKINETIC BEHAVIOR AND ESCA STUDIES [J].
BERGSTROM, L ;
BOSTEDT, E .
COLLOIDS AND SURFACES, 1990, 49 (3-4) :183-197
[5]   Characterization of nitride coatings by XPS [J].
Bertóti, I .
SURFACE & COATINGS TECHNOLOGY, 2002, 151 :194-203
[6]   COPPER CHROMITE CATALYSTS - XPS STRUCTURE ELUCIDATION AND CORRELATION WITH CATALYTIC ACTIVITY [J].
CAPECE, FM ;
DICASTRO, V ;
FURLANI, C ;
MATTOGNO, G ;
FRAGALE, C ;
GARGANO, M ;
ROSSI, M .
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1982, 27 (02) :119-128
[7]   Modern approaches to marine antifouling coatings [J].
Chambers, L. D. ;
Stokes, K. R. ;
Walsh, F. C. ;
Wood, R. J. K. .
SURFACE & COATINGS TECHNOLOGY, 2006, 201 (06) :3642-3652
[8]   Mechanical and tribological properties of nanocomposite TiSiN coatings [J].
Cheng, Y. H. ;
Browne, T. ;
Heckerman, B. ;
Meletis, E. I. .
SURFACE & COATINGS TECHNOLOGY, 2010, 204 (14) :2123-2129
[9]   X-RAY PHOTOELECTRON STUDY OF TIN/SIO2 AND TIN/SI INTERFACES [J].
CHOURASIA, AR ;
CHOPRA, DR .
THIN SOLID FILMS, 1995, 266 (02) :298-301
[10]   Microstructure and antibacterial properties of AISI 420 stainless steel implanted by copper ions [J].
Dan, ZG ;
Ni, HW ;
Xu, BF ;
Xiong, J ;
Xiong, PY .
THIN SOLID FILMS, 2005, 492 (1-2) :93-100