Accessing Zinc Monohydride Cations through Coordinative Interactions

被引：106

作者：

Lummis, Paul A. ^{[1
]}

Momeni, Mohammad R. ^{[1
]}

Lui, Melanie W. ^{[1
]}

McDonald, Robert ^{[1
]}

Ferguson, Michael J. ^{[1
]}

Miskolzie, Mark ^{[1
]}

Brown, Alex ^{[1
]}

Rivard, Eric ^{[1
]}

机构：

[1] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2014年 / 53卷 / 35期

基金：

加拿大创新基金会; 加拿大自然科学与工程研究理事会;

关键词：

cations; homogeneous catalysis; hydrides; N-heterocyclic carbene; zinc; X-RAY; HYDRIDE; COMPLEXES; ZN; HYDROSILYLATION; DERIVATIVES; CONVENIENT; GENERATION; REACTIVITY; HALIDES;

D O I：

10.1002/anie.201404611

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We present isolable examples of formal zinc hydride cations supported by N-heterocyclic carbene (NHC) donors, and investigate the dual electrophilic and nucleophilic (hydridic) character of the encapsulated [ZnH](+) units by computational methods and preliminary hydrosilylation catalysis.

引用

页码：9347 / 9351

页数：5

共 52 条

[1] Stable Complexes of Parent Digermene: An Inorganic Analogue of Ethylene [J].

Al-Rafia, S. M. Ibrahim ;

Momeni, Mohammad R. ;

Ferguson, Michael J. ;

McDonald, Robert ;

Brown, Alex ;

Rivard, Eric .

ORGANOMETALLICS, 2013, 32 (22) :6658-6665

[2] Preparation and Structures of Group 12 and 14 Element Halide-Carbene Complexes [J].

Al-Rafia, S. M. Ibrahim ;

Lummis, Paul A. ;

Swarnakar, Anindya K. ;

Deutsch, Kelsey C. ;

Ferguson, Michael J. ;

McDonald, Robert ;

Rivard, Eric .

AUSTRALIAN JOURNAL OF CHEMISTRY, 2013, 66 (10) :1235-1245

[3] Efficient generation of stable adducts of Si(II) dihydride using a donor-acceptor approach [J].

Al-Rafia, S. M. Ibrahim ;

Malcolm, Adam C. ;

McDonald, Robert ;

Ferguson, Michael J. ;

Rivard, Eric .

CHEMICAL COMMUNICATIONS, 2012, 48 (09) :1308-1310

[4] Trapping the Parent Inorganic Ethylenes H2SiGeH2 and H2SiSnH2 in the Form of Stable Adducts at Ambient Temperature [J].

Al-Rafia, S. M. Ibrahim ;

Malcolm, Adam C. ;

McDonald, Robert ;

Ferguson, Michael J. ;

Rivard, Eric .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (36) :8354-8357

[5] Intercepting low oxidation state main group hydrides with a nucleophilic N-heterocyclic olefin [J].

Al-Rafia, S. M. Ibrahim ;

Malcolm, Adam C. ;

Liew, Sean K. ;

Ferguson, Michael J. ;

McDonald, Robert ;

Rivard, Eric .

CHEMICAL COMMUNICATIONS, 2011, 47 (24) :6987-6989

[6] Stabilization of the Heavy Methylene Analogues, GeH2 and SnH2, within the Coordination Sphere of a Transition Metal [J].

Al-Rafia, S. M. Ibrahim ;

Malcolm, Adam C. ;

Liew, Sean K. ;

Ferguson, Michael J. ;

Rivard, Eric .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (04) :777-779

[7]

Al-Rafia SMI, 2011, ANGEW CHEM, V123, P8504

[8]

Alder R.W., 1996, ANGEW CHEM, V108, P1211

[9] Bis(diisopropylamino)carbene [J].

Alder, RW ;

Allen, PR ;

Murray, M ;

Orpen, AG .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (10) :1121-1123

[10] Nickel Nanoparticles in Hydrogen Transfer Reactions [J].

Alonso, Francisco ;

Riente, Paola ;

Yus, Miguel .

ACCOUNTS OF CHEMICAL RESEARCH, 2011, 44 (05) :379-391

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