Investigation of reactive intermediates of chemical reactions in solution by electrospray ionization mass spectrometry: radical chain reactions

被引：0
作者：
Griep-Raming, J
Meyer, S
Bruhn, T
Metzger, JO
机构：
[1] Carl von Ossietzky Univ Oldenburg, Fachbereich Chem, D-26111 Oldenburg, Germany
[2] Thermo Finnigan MAT GmbH, D-28197 Bremen, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2002年 / 41卷 / 15期
关键词：
carbocations; mass spectrometry; radicals; reactive intermediates; scandium;
D O I：
10.1002/1521-3773(20020802)41:15<2738::AID-ANIE2738>3.0.CO;2-X
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A useful tool for the investigation of synthetically important tributyltin-mediated radical chain reactions is electrospray ionization mass spectrometry (ESIMS). A microreaction system is coupled online to the ESI source. Transient radicals were detected unambiguously by using MS/ MS methods (see picture).
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页码：2738 / +
页数：6
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