Photocatalytic Degradation of Anthracene in Closed System Reactor

被引:35
|
作者
Karam, Faiq F. [1 ]
Hussein, Falah H. [2 ]
Baqir, Sadiq J. [2 ]
Halbus, Ahmed F. [2 ]
Dillert, Ralf [3 ]
Bahnemann, Detelf [3 ]
机构
[1] Al Qadisiya Univ, Coll Sci, Dept Chem, Al Deewaniya 58002, Iraq
[2] Babylon Univ, Coll Sci, Dept Chem, Hilla 51002, Iraq
[3] Leibniz Univ Hannover, Inst Tech Chem, D-30167 Hannover, Germany
关键词
POLYCYCLIC AROMATIC-HYDROCARBONS; TITANIUM-DIOXIDE; SOIL SURFACES; TIO2; EXTRACTION; PAHS;
D O I
10.1155/2014/503825
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Polycyclic aromatic hydrocarbons (PAHs) represent a large class of persistent organic pollutants in an environment of special concern because they have carcinogenic and mutagenic activity. In this paper, we focus on and discuss the effect of different parameters, for instance, initial concentration of Anthracene, temperature, and light intensity, on the degradation rate. These parameters were adjusted at pH 6.8 in the presence of the semiconductor materials (TiO2) as photocatalysts overUVlight. The main product of Anthracene photodegradation is 9,10-Anthraquinone which isidentified and compared with the standard compound by GC-MS. Our results indicate that the optimum conditions for the best rate of degradation are 25 ppm concentration of Anthracene, regulating the reaction vessel at 308.15 K and 2.5 mW/cm(2) of light intensity at 17 5mg/100 mL of titanium dioxide (P25).
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页数:6
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