Hydrothermal synthesis of a new perovskite-type bismuth oxide: Ba0.96Bi0.86O2.59(OH)0.41

被引：17

作者：

Jiang, Hong ^{[1
]}

Kumada, Nobuhiro ^{[1
]}

Yonesaki, Yoshinori ^{[1
]}

Takei, Takahiro ^{[1
]}

Kinomura, Nobukazu ^{[1
]}

机构：

[1] Yamanashi Univ, Dept Res Interdisciplinary Grad Sch Med & Engn, Kofu, Yamanashi 4008511, Japan

来源：

JOURNAL OF THE CERAMIC SOCIETY OF JAPAN | 2009年 / 117卷 / 1362期

关键词：

Perovskite; Hydrothermal; Bismuth oxide; CRYSTAL-STRUCTURE; NEUTRON-DIFFRACTION; BAPB1-XBIXO3; SYSTEM; SUPERCONDUCTIVITY;

D O I：

10.2109/jcersj2.117.214

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

A new perovskite-type oxide, Ba0.96Bi0.86O2.59(OH)(0.41)) was prepared by low temperature hydrothermal reaction using NaBiO3 center dot nH(2)O and Ba(OH)(2)center dot 8H(2)O as starting materials. The crystal structure of this compound was refined by single crystal X-ray diffraction data, and the structure refinement with the space group Pm3m (#221) led to R-w = 0.035 and R = 0.054 for all renections. This compound had the perovskite-type structure with the cubic cell of a = 4.2995(5) angstrom. The magnetic susceptibility of this compound exhibited no superconductive behavior down to 4 K. (C) 2009 The Ceramic Society of Japan. All rights reserved.

引用

页码：214 / 216

页数：3

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