Total Synthesis of (±)-5-Deoxystrigol via Reductive Carbon-Carbon Bond Formation

被引：14

作者：

Shoji, Mitsuru ^{[1
]}

Suzuki, Eriko ^{[1
]}

Ueda, Minoru ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 74卷 / 10期

关键词：

SEED-GERMINATION STIMULANT; DESS-MARTIN PERIODINANE; STRIGA-LUTEA LOUR; PLANT BIOREGULATORS; SORGHUM-BICOLOR; SECONDARY ALCOHOLS; HINDERED CARBON; OROBANCHE-MINOR; 8; STEREOISOMERS; OXIDATION;

D O I：

10.1021/jo9002085

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The total synthesis of 5-deoxystrigol was successfully carried out via the regioselective coupling reaction between the aluminum ate complex of an alkyne and an epoxide and the two reductive carbon-carbon bond formations in the presence of transition metals as key steps.

引用

页码：3966 / 3969

页数：4

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