Total Synthesis of (±)-5-Deoxystrigol via Reductive Carbon-Carbon Bond Formation

被引：14
|
作者：
Shoji, Mitsuru [1 ]
Suzuki, Eriko [1 ]
Ueda, Minoru [1 ]
机构：
[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 74卷 / 10期
关键词：
SEED-GERMINATION STIMULANT; DESS-MARTIN PERIODINANE; STRIGA-LUTEA LOUR; PLANT BIOREGULATORS; SORGHUM-BICOLOR; SECONDARY ALCOHOLS; HINDERED CARBON; OROBANCHE-MINOR; 8; STEREOISOMERS; OXIDATION;
D O I：
10.1021/jo9002085
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The total synthesis of 5-deoxystrigol was successfully carried out via the regioselective coupling reaction between the aluminum ate complex of an alkyne and an epoxide and the two reductive carbon-carbon bond formations in the presence of transition metals as key steps.
引用
收藏
页码：3966 / 3969
页数：4
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