Unusual complexation of nitrate with lanthanides in a wet ionic liquid: a new approach for aqueous separation of trivalent f-elements using an ionic liquid as solvent

被引：16

作者：

Ansari, Seraj A. ^{[1
]}

Liu, Lisheng ^{[1
]}

Phuong Diem Dau ^{[1
]}

Gibson, John K. ^{[1
]}

Rao, Linfeng ^{[1
]}

机构：

[1] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Chem Sci, Berkeley, CA 94720 USA

来源：

RSC ADVANCES | 2014年 / 4卷 / 72期

关键词：

ACTINIDE IONS; VARIABLE TEMPERATURES; EQUILIBRIUM-CONSTANTS; SYSTEMS; EXAFS;

D O I：

10.1039/c4ra08252d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The energetics of lanthanide nitrate complexation in a wet ionic liquid (IL; saturated with water as seen in the aqueous separation process) differs entirely from that in dry IL. A new approach to design more effective strategies for separation of actinides and lanthanides using an IL as a solvent has been revealed.

引用

页码：37988 / 37991

页数：4

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