Milling-induced phenomena in SrTiO3

被引:9
作者
Psiuk, B. [1 ]
Szade, J. [2 ]
Wrzalik, R. [2 ]
Osadnik, M. [3 ]
Wala, T. [1 ]
机构
[1] Inst Ceram & Bldg Mat, Refractory Mat Div, PL-44100 Gliwice, Poland
[2] Silesian Univ, A Chetkowski Inst Phys, PL-40007 Katowice, Poland
[3] Inst Nonferrous Met, PL-44100 Gliwice, Poland
关键词
Milling; UV-vis; Specific surface area; SrTiO3; Band gap states; PHOTOCATALYTIC ACTIVITY; SURFACE; PHOTOLUMINESCENCE; ION;
D O I
10.1016/j.ceramint.2013.12.019
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The effect of milling was studied for the SrTiO3 samples. We show that by solid state reaction and subsequent milling it is possible to produce SrTiO3 powders with high specific surface area exceeding 10 m(2)/g. However, grinding process induced changes in chemical composition and electronic structure of surface layers of SrTiO3 crystal grains. The changes are discussed in the context of kinetic demixing phenomena and partial amorphization of the surface region. (c) 2013 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码:6957 / 6961
页数:5
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