Effect of cerium content on microstructure and hydrogen storage performance of Ti24Cr17.5V50Fe8.5Cex (x=0-1.0) alloys

被引:16
作者
Mi Jing [1 ]
Liu Xiaopeng [1 ]
Li Yan [1 ]
Jiang Lijun [1 ]
Li Zhinian [1 ]
Huang Zhuo [1 ]
Wang Shumao [1 ]
机构
[1] Gen Res Inst Nonferrous Met, Energy Mat & Technol Res Inst, Beijing 100088, Peoples R China
关键词
hydrogen storage materials; Ti-Cr-V alloys; BCC alloys; rare earths; ABSORPTION PROPERTIES; PHASE ALLOYS; CAPACITY; SYSTEM;
D O I
10.1016/S1002-0721(08)60211-2
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Effect of Ce addition on microstructure and hydrogen storage performance of Ti24Cr17.5V50Fe8.5Cex (x=0, 0.5at.%, 0.8at.% and 1.0at.%) alloys was studied by X-ray diffraction, scanning electron microscopy and P-C-isotherm measurements. The results indicated that Ce addition was a useful way to improve the flatness of the plateau and increase hydrogen storage capacity of Ti24Cr17.5V50Fe8.5 alloy. It was indicated that both homogenization of composition and increase of hydrogen diffusion coefficient were the main reasons for improving the hydrogen storage performance of Ti24Cr17.5V50Fe8.5Cex alloys.
引用
收藏
页码:154 / 158
页数:5
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