Infrared spectra of He-, Ne-, and Ar-C6D6

被引：9

作者：

George, J. ^{[1
]}

McKellar, A. R. W. ^{[2
]}

Moazzen-Ahmadi, N. ^{[1
]}

机构：

[1] Univ Calgary, Dept Phys & Astron, Calgary, AB T2N 1N4, Canada

[2] Natl Res Council Canada, Ottawa, ON K1A 0R6, Canada

来源：

CHEMICAL PHYSICS LETTERS | 2014年 / 610卷

基金：

加拿大自然科学与工程研究理事会;

关键词：

BENZENE-AR COMPLEX; ENHANCED 2-PHOTON IONIZATION; DER-WAALS COMPLEX; GROUND-STATE; ROTATIONAL SPECTRA; HIGH-RESOLUTION; DIPOLE-MOMENT; SPECTROSCOPY; BAND; KR;

D O I：

10.1016/j.cplett.2014.06.059

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Spectra of He-, Ne- and Ar-C6D6 in the region of the v(12) fundamental of C6D6 are observed in a pulsed supersonic jet expansion using a tunable optical parametric oscillator laser source. These are the first reported infrared spectra of rare gas-benzene complexes and the first observation in any region for He- and Ne-C6D6. Two bands are studied for each complex: the v(12) fundamental itself (approximate to 2289 cm(-1)) and the v(2) + v(13) combination band (approximate to 2276 cm(-1)) which are coupled by a Fermi resonance. Effective intermolecular separations of 3.593(1) and 3.455(1) angstrom are obtained for He- and Ne-C6D6, respectively, consistent with previous ultraviolet and microwave results for the analogous C6H6 complexes. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：121 / 124

页数：4

共 23 条

[1]

[Anonymous], PGOPHER PROGRAM SIMU

[2] ROTATIONAL SPECTRA AND STRUCTURES OF RG-C6H6-H2O TRIMERS AND THE NE-C6H6 DIMER (RG=NE, AR, OR KR) [J].

ARUNAN, E ;

EMILSSON, T ;

GUTOWSKY, HS .

JOURNAL OF CHEMICAL PHYSICS, 1994, 101 (02) :861-868

[3] ROTATIONAL ANALYSIS OF THE 1B2U(PI-PI-STAR) ]-1A1G(610) BAND OF BENZENE AND HELIUM-BENZENE VANDERWAALS COMPLEXES IN A SUPERSONIC JET [J].

BECK, SM ;

LIVERMAN, MG ;

MONTS, DL ;

SMALLEY, RE .

JOURNAL OF CHEMICAL PHYSICS, 1979, 70 (01) :232-237

[4] The Benzene-Argon Ground-State Intermolecular Potential Energy Surface Revisited [J].

Bouzon Capelo, Silvia ;

Fernandez, Berta ;

Koch, Henrik ;

Felker, Peter M. .

JOURNAL OF PHYSICAL CHEMISTRY A, 2009, 113 (17) :5212-5216

[5] INTERMOLECULAR DYNAMICS OF BENZENE RARE-GAS COMPLEXES AS DERIVED FROM MICROWAVE-SPECTRA [J].

BRUPBACHER, T ;

MAKAREWICZ, J ;

BAUDER, A .

JOURNAL OF CHEMICAL PHYSICS, 1994, 101 (11) :9736-9746

[6] ROTATIONAL SPECTRUM AND DIPOLE-MOMENT OF THE BENZENE-ARGON VANDERWAALS COMPLEX [J].

BRUPBACHER, T ;

BAUDER, A .

CHEMICAL PHYSICS LETTERS, 1990, 173 (5-6) :435-438

[7] Nitrous oxide dimer: Observation of a new polar isomer [J].

Dehghani, M. ;

Afshari, Mahin ;

Abusara, Z. ;

Moazzen-Ahmadi, N. ;

McKellar, A. R. W. .

JOURNAL OF CHEMICAL PHYSICS, 2007, 126 (16)

[8] Sub-Doppler rotationally resolved spectroscopy of the S1 1B2u(ν6=1) ← S0 1A1g (ν=0) bands of benzene and benzene-d6 [J].

Doi, A ;

Baba, M ;

Kasahara, S ;

Katô, H .

JOURNAL OF MOLECULAR SPECTROSCOPY, 2004, 227 (02) :180-186

[9]

Gordy W., 1970, MICROWAVE MOL SPECTR, P147

[10] Sub-Doppler electronic spectra of the benzene-(He)n complexes [J].

Hayashi, Masato ;

Ohshima, Yasuhiro .

CHEMICAL PHYSICS, 2013, 419 :131-137

← 1 2 3 →