Towards a remote IR fiber-optic sensor system for the determination of chlorinated hydrocarbons in water

被引:67
作者
Jakusch, M [1 ]
Mizaikoff, B [1 ]
Kellner, R [1 ]
机构
[1] TEL AVIV UNIV,RAYMOND & BEVERLY SACKLER FAC EXACT SCI,SCH PHYS & ASTRON,IL-69978 TEL AVIV,ISRAEL
关键词
Fourier transform infrared spectroscopy; fiber evanescent-wave spectroscopy; silver halide; chlorinated hydrocarbons;
D O I
10.1016/S0925-4005(97)80175-X
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A laboratory prototype of a mid-infrared (MIR) fiber-optic sensor system capable of remote on-site and real-time determination of chlorinated hydrocarbons (CHCs) in water has been developed. The system is based upon fiber evanescent-wave spectroscopy (FEWS) and consists of silver halide fibers that are coupled to a portable Fourier transform infrared (FTIR) spectrometer. These fibers serve both as signal transfer lines and as sensing elements. In the latter case they are coated with thin films of ethylene/propylene copolymer for the purposes of enrichment of the analytes and exclusion of water. A detection limit for tetrachloroethylene of 300 ppb has been achieved with a total contact time between sample and sensor of 10 min.
引用
收藏
页码:83 / 87
页数:5
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