Bio-reduction of graphene oxide using drained water from soaked mung beans (Phaseolus aureus L.). and its application as energy storage electrode material

被引:93
作者
Jana, Milan [1 ,2 ]
Saha, Sanjit [1 ]
Khanra, Partha [3 ]
Murmu, Naresh Chandra [1 ]
Srivastava, Suneel Kumar [4 ]
Kuila, Tapas [1 ]
Lee, Joong Hee [3 ]
机构
[1] CSIR, Cent Mech Engn Res Inst, Surface Engn & Tribol Div, Durgapur 713209, India
[2] Acad Sci & Innovat Res AcSIR, New Delhi 110001, India
[3] Chonbuk Natl Univ, Adv Mat Res Inst BIN Fus Technol, Dept BIN Fus Technol, BK Plus Global Program, Jeonju 561756, Jeonbuk, South Korea
[4] Indian Inst Technol, Dept Chem, Kharagpur 721302, W Bengal, India
来源
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS | 2014年 / 186卷
关键词
Graphene oxide; Green reduction; Mung bean; Raman spectroscopy; Electrochemical performances; HIGH-PERFORMANCE; EFFICIENT REDUCTION; GRAPHITE OXIDE; GREEN APPROACH; CARBON; COMPOSITE; FUNCTIONALIZATION; SUPERCAPACITORS; SHEETS; PSEUDOCAPACITANCE;
D O I
10.1016/j.mseb.2014.03.004
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Green reduction of graphene oxide (GO) using drained water from soaked mung beans (Phaseolus aureus L.) has been demonstrated. In comparison to the toxic and hazardous reducing chemicals, the drained water from soaked mung beans (P. aureus L.) is completely green reducing agent, the reduction process is very simple and cost effective. The removal of oxygen containing functional groups of GO has been confirmed by UV-vis, Fourier transform infrared and X-ray photoelectron spectroscopy analysis. Morphological characterization of rGO has been performed by atomic force and transmission electron microscopy analysis. Electrochemical performances of rGO have been evaluated by cyclic voltammetry (CV), charge-discharge and electrochemical impedance spectroscopy techniques. The specific capacitance (SC) of rGO has been found to be 137 Fg(-1) at a current density of 1.3 A g(-1). The retention in SC is more than 98% after 1000 charge-discharge cycles suggesting long-term electrochemical cyclic stability as supercapacitor electrode materials. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:33 / 40
页数:8
相关论文
共 64 条
[1]   The Role of Oxygen during Thermal Reduction of Graphene Oxide Studied by Infrared Absorption Spectroscopy [J].
Acik, Muge ;
Lee, Geunsik ;
Mattevi, Cecilia ;
Pirkle, Adam ;
Wallace, Robert M. ;
Chhowalla, Manish ;
Cho, Kyeongjae ;
Chabal, Yves .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (40) :19761-19781
[2]   Efficient synthesis of graphene sheets using pyrrole as a reducing agent [J].
Amarnath, Chellachamy Anbalagan ;
Hong, Chang Eui ;
Kim, Nam Hoon ;
Ku, Bon-Cheol ;
Kuila, Tapas ;
Lee, Joong Hee .
CARBON, 2011, 49 (11) :3497-3502
[3]   Graphene: synthesis and applications [J].
Avouris, Phaedon ;
Dimitrakopoulos, Christos .
MATERIALS TODAY, 2012, 15 (03) :86-97
[4]   Dual role of glycine as a chemical functionalizer and a reducing agent in the preparation of graphene: an environmentally friendly method [J].
Bose, Saswata ;
Kuila, Tapas ;
Mishra, Ananta Kumar ;
Kim, Nam Hoon ;
Lee, Joong Hee .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (19) :9696-9703
[5]   A facile method to prepare stable noncovalent functionalized graphene solution with thionine [J].
Chen, Cao ;
Zhai, Wentao ;
Lu, Dingding ;
Zhang, Haobin ;
Zheng, Wenge .
MATERIALS RESEARCH BULLETIN, 2011, 46 (04) :583-587
[6]   An environment-friendly preparation of reduced graphene oxide nanosheets via amino acid [J].
Chen, Dezhi ;
Li, Lidong ;
Guo, Lin .
NANOTECHNOLOGY, 2011, 22 (32)
[7]   High-performance supercapacitors based on a graphene-activated carbon composite prepared by chemical activation [J].
Chen, Yao ;
Zhang, Xiong ;
Zhang, Haitao ;
Sun, Xianzhong ;
Zhang, Dacheng ;
Ma, Yanwei .
RSC ADVANCES, 2012, 2 (20) :7747-7753
[8]   High performance supercapacitors based on reduced graphene oxide in aqueous and ionic liquid electrolytes [J].
Chen, Yao ;
Zhang, Xiong ;
Zhang, Dacheng ;
Yu, Peng ;
Ma, Yanwei .
CARBON, 2011, 49 (02) :573-580
[9]   Stable dispersions of graphene and highly conducting graphene films: a new approach to creating colloids of graphene monolayers [J].
Chen, Yao ;
Zhang, Xiong ;
Yu, Peng ;
Ma, Yanwei .
CHEMICAL COMMUNICATIONS, 2009, (30) :4527-4529
[10]   Characterization of amorphous and nanocrystalline carbon films [J].
Chu, PK ;
Li, LH .
MATERIALS CHEMISTRY AND PHYSICS, 2006, 96 (2-3) :253-277