The first radical salt of the polyoxometalate cluster [P2W18O62](6 theta) with bis(ethylenedithio)tetrathiafulvalene (ET): ET(11)[P2W18O62]center dot 3H(2)O

被引：47

作者：

Coronado, E ^{[1
]}

GalanMascaros, JR ^{[1
]}

GimenezSaiz, C ^{[1
]}

GomezGarcia, CJ ^{[1
]}

Laukhin, VN ^{[1
]}

机构：

[1] CSIC,ICMB,E-08193 BELLATERRA,SPAIN

来源：

ADVANCED MATERIALS | 1996年 / 8卷 / 10期

关键词：

D O I：

10.1002/adma.19960081005

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The study of organic donor-inorganic cluster hybrids has been extended to polyoxometalates with higher nuclearities and different shapes using the heteropolyanion [P2W18O62](6 circle minus) combined with bis(ethyl-enedithio)tetrathiafulvalene. The resulting hybrid material is unique in several respects: the new radical salt has an unprecedented stoichiometry and beta type packing; it is the first well-characterized radical salt of a polymetalate to exhibit metallic behavior. Further possibilities for investigation are briefly outlined.

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页码：801 / &

页数：4

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