Nanoscience for Art Conservation: Oil-in-Water Microemulsions Embedded in a Polymeric Network for the Cleaning of Works of Art

被引：55
作者：
Carretti, Emiliano
Fratini, Emiliano
Berti, Debora
Dei, Luigi
Baglioni, Piero [1 ]
机构：
[1] Univ Florence, Dept Chem, I-50019 Florence, Italy
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 47期
关键词：
art conservation; microemulsions; polymers; surface analysis; small-angle X-ray scattering; SOLUBILIZATION; ORGANOGELS; ACRYLAMIDE; MICELLES; RHEOLOGY; GELS;
D O I：
10.1002/anie.200904244
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
As good as new: Oil-in-water nanocontainers within an aqueous polymer network were effective for the low-impact selective cleaning of painted and gilded surfaces. Interactions with the polymer (black in the schematic illustration) did not alter the structure of the microemulsion nanodroplets (light blue and red) significantly. A photograph of an equilibrated mixture of the microemulsion and the polymer is shown. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：8966 / 8969
页数：4
相关论文
共 48 条
  • [1] Three-phase microemulsion/sol-gel system for aqueous catalytic hydroformylation of hydrophobic alkenes
    Abu-Reziq, R
    Avnir, D
    Blum, J
    [J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2005, 2005 (17) : 3640 - 3642
  • [2] [Anonymous], ANGEW CHEM, DOI 10.1002/ange.200702427
  • [3] Soft and hard nanomaterials for restoration and conservation of cultural heritage
    Baglioni, P
    Giorgi, R
    [J]. SOFT MATTER, 2006, 2 (04) : 293 - 303
  • [4] BARNES H. A., 2000, HDB ELEMENTARY RHEOL, P56
  • [5] Acrylamide and butyl acrylate polymerization in Winsor IV (w/o) and Winsor I (o/w) microemulsions
    Barton, J
    Capek, I
    [J]. MACROMOLECULES, 2000, 33 (15) : 5353 - 5357
  • [6] Synthesis and characterization of surfactant and silica-coated cobalt ferrite nanoparticles
    Bonini, M
    Wiedenmann, A
    Baglioni, P
    [J]. PHYSICA A-STATISTICAL MECHANICS AND ITS APPLICATIONS, 2004, 339 (1-2) : 86 - 91
  • [7] A new way to prepare nanostructured materials: Flame spraying of microemulsions
    Bonini, M
    Bardi, U
    Berti, D
    Neto, C
    Baglioni, P
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (24) : 6178 - 6183
  • [8] Acrylamide-Based Magnetic Nanosponges: A New Smart Nanocomposite Material
    Bonini, Massimo
    Lenz, Sebastian
    Falletta, Ester
    Ridi, Francesca
    Carretti, Emiliano
    Fratini, Emiliano
    Wiedenmann, Albrecht
    Baglioni, Piero
    [J]. LANGMUIR, 2008, 24 (21) : 12644 - 12650
  • [9] Nanomagnetic sponges for the cleaning of works of art
    Bonini, Massimo
    Lenz, Sebastian
    Giorgi, Rodorico
    Baglioni, Piero
    [J]. LANGMUIR, 2007, 23 (17) : 8681 - 8685
  • [10] Bourrel M., 1988, MICROEMULSIONS RELAT
12345