Mechanical characterization and chemical resistances of cured unsaturated polyester resins modified with vinyl ester resins based on recycled poly(ethylene terephthalate)

被引：14
作者：
Atta, Ayman M. [1 ]
Abdel-Raouf, Manar E. [1 ]
Elsaeed, Shimaa M. [1 ]
Abdel-Azim, Abdel-Azim A. [1 ]
机构：
[1] Egyptian Petr Res Inst, Cairo 11727, Egypt
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 2007年 / 103卷 / 05期
关键词：
unsaturated polyesters; poly(ethylene terephthalate); vinyl ester resins; recycling; curing behaviors; mechanical characteristics;
D O I：
10.1002/app.25196
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Unsaturated polyester resin (UP) was prepared from glycolyzed oligomer of poly(ethylene terephthalate) (PET) waste based on diethylene glycol (DEG). New diacrylate and dimethacrylate vinyl ester resins prepared from glycolysis of PET with tetraethylene glycol were blended with UP to study the mechanical characteristics of the cured UP. The vinyl ester resins were used as crosslinking agents for unsaturated polyester resin diluted with styrene, using free-radical initiator and accelerator. The mechanical properties of the cured UP resins were evaluated. The compressive properties of the cured UP/styrene resins in the presence of different vinyl ester concentrations were evaluated. Increasing the vinyl ester content led to a pronounced improvement in the compression strength. The chemical resistances of the cured resins were evaluated through hot water, solvents, acid, and alkali resistance measurements. (c) 2006 Wiley Periodicals, Inc.
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页码：3175 / 3182
页数：8
相关论文
共 38 条
  • [21] ODIAN G, 1991, PRINCIPLES POLYM, pCH6
  • [22] FREE-RADICAL CROSS-LINKING COPOLYMERIZATION - EFFECT OF CYCLIZATION ON DIFFUSION-CONTROLLED TERMINATION AT LOW CONVERSION
    OKAY, O
    NAGHASH, HJ
    CAPEK, I
    [J]. POLYMER, 1995, 36 (12) : 2413 - 2419
  • [23] Park DJ, 1998, J APPL POLYM SCI, V67, P1345, DOI 10.1002/(SICI)1097-4628(19980222)67:8<1345::AID-APP1>3.0.CO
  • [24] 2-E
  • [25] PAUL E, 1973, IND MAINTENANCE PAIN, pCH5
  • [26] Rebeiz K.S., 1991, J MAT ED, V13, P441
  • [27] ROSKOTT L, 1978, 33 ANN C REINF PLAST
  • [28] Schulze U, 1997, J APPL POLYM SCI, V64, P527, DOI 10.1002/(SICI)1097-4628(19970418)64:3<527::AID-APP9>3.0.CO
  • [29] 2-M
  • [30] STOCKMAYER HW, 1945, J CHEM PHYS, V11, P45
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