1,3-Bis(pyridineylidene)isoindoline: an isoindoline chelate with a stretched electronic structure

被引：8
作者：
Gaire, Sanjay [1 ]
Schrage, Briana R. [1 ]
Nemykin, Victor N. [2 ]
Ziegler, Christopher J. [1 ]
机构：
[1] Univ Akron, Dept Chem, Akron, OH 44325 USA
[2] Univ Tennessee, Dept Chem, Knoxville, TN 37994 USA
来源：
DALTON TRANSACTIONS | 2021年 / 50卷 / 03期
关键词：
PINCER LIGAND; COMPLEXES; CHEMISTRY; CD(II);
D O I：
10.1039/d0dt04347h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A bridging carbon analog of the well-studied bis(pyridyl)iminoisoindoline (BPI) can be produced via a one step reaction between diiminoisoindoline and pyridine-2-acetonitrile. The resultant bis(pyridineylidene)isoindoline (BPYI) is structurally analogous to BPI and can readily form metal complexes. However, it exhibits a markedly different electronic structure with intense absorption bands in the visible region of the spectrum.
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收藏
页码：826 / 829
页数：4
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