An amino-decorated NbO-type metal-organic framework for high C2H2 storage and selective CO2 capture

被引：50

作者：

Cai, Jianfeng ^{[1
]}

Wang, Huizhen ^{[1
]}

Wang, Hailong ^{[2
]}

Duan, Xing ^{[1
]}

Wang, Zhiyu ^{[1
]}

Cui, Yuanjing ^{[1
]}

Yang, Yu ^{[1
]}

Chen, Banglin ^{[1
,2
,3
]}

Qian, Guodong ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Mat Sci & Engn, Cyrus Tang Ctr Sensor Mat & Applicat, State Key Lab Silicon Mat, Hangzhou 310027, Zhejiang, Peoples R China

[2] Univ Texas San Antonio, Dept Chem, San Antonio, TX 78249 USA

[3] King Abdulaziz Univ, Dept Chem, Fac Sci, Jeddah 22254, Saudi Arabia

来源：

RSC ADVANCES | 2015年 / 5卷 / 94期

基金：

中国国家自然科学基金;

关键词：

CARBON-DIOXIDE CAPTURE; HIGH METHANE STORAGE; BASIC PYRIDYL SITES; HIGH ACETYLENE; HIGH-CAPACITY; ADSORPTIVE SEPARATION; HYDROGEN ADSORPTION; FUNCTIONAL-GROUPS; ACYLAMIDE GROUPS; H-2; ADSORPTION;

D O I：

10.1039/c5ra12700a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel amino-decorated NbO-type metal-organic framework [Cu-2(C22H11NO8)(H2O)(2)]center dot(DMF)(6)center dot(H2O), (ZJU-8, ZJU = Zhejiang University; DMF = N,N-dimethylformamide) has been synthesized and structurally characterized. The activated ZJU-8a exhibits both a high C2H2 uptake capacity (195 cm(3) g(-1) at 1 bar) and a moderately high adsorption selectivity for CO2 over N-2 (12.27) and CH4 (7.38) at room temperature.

引用

页码：77417 / 77422

页数：6

共 86 条

[71] Open Metal Sites within Isostructural Metal-Organic Frameworks for Differential Recognition of Acetylene and Extraordinarily High Acetylene Storage Capacity at Room Temperature [J].

Xiang, Shengchang ;

Zhou, Wei ;

Zhang, Zhangjing ;

Green, Mark A. ;

Liu, Yun ;

Chen, Banglin .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (27) :4615-4618

[72] Exceptionally High Acetylene Uptake in a Microporous Metal-Organic Framework with Open Metal Sites [J].

Xiang, Shengchang ;

Zhou, Wei ;

Gallegos, Jose M. ;

Liu, Yun ;

Chen, Banglin .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (34) :12415-12419

[73] A 2D metal-organic framework composed of a bi-functional ligand with ultra-micropores for post-combustion CO2 capture [J].

Xu, Guodong ;

Peng, Yongwu ;

Hu, Zhigang ;

Yuan, Daqiang ;

Donnadieu, Bruno ;

Zhao, Dan ;

Cheng, Hansong .

RSC ADVANCES, 2015, 5 (59) :47384-47389

[74]

Xu H., 2013, J MATER CHEM A, V1, P77

[75] A cationic microporous metal-organic framework for highly selective separation of small hydrocarbons at room temperature [J].

Xu, Hui ;

Cai, Jianfeng ;

Xiang, Shengchang ;

Zhang, Zhangjing ;

Wu, Chuande ;

Rao, Xiangtang ;

Cui, Yuanjing ;

Yang, Yu ;

Krishna, Rajamani ;

Chen, Banglin ;

Qian, Guodong .

JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (34) :9916-9921

[76] Modulating the packing of [Cu24(isophthalate)24] cuboctahedra in a triazole-containing metal-organic polyhedral framework [J].

Yan, Yong ;

Suyetin, Mikhail ;

Bichoutskaia, Elena ;

Blake, Alexander J. ;

Allan, David R. ;

Barnett, Sarah A. ;

Schroeder, Martin .

CHEMICAL SCIENCE, 2013, 4 (04) :1731-1736

[77]

Yang SH, 2012, NAT MATER, V11, P710, DOI [10.1038/NMAT3343, 10.1038/nmat3343]

[78] Enhancement of H2 Adsorption in Coordination Framework Materials by Use of Ligand Curvature [J].

Yang, Sihai ;

Lin, Xiang ;

Dailly, Anne ;

Blake, Alexander J. ;

Hubberstey, Peter ;

Champness, Neil R. ;

Schroeder, Martin .

CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (19) :4829-4835

[79] Sequential Linker Installation: Precise Placement of Functional Groups in Multivariate Metal-Organic Frameworks [J].

Yuan, Shuai ;

Lu, Weigang ;

Chen, Ying-Pin ;

Zhang, Qiang ;

Liu, Tian-Fu ;

Feng, Dawei ;

Wang, Xuan ;

Qin, Junsheng ;

Zhou, Hong-Cai .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (09) :3177-3180

[80] A nitro-decorated NbO-type metal-organic framework with a highly selective CO2 uptake and CH4 storage capacity [J].

Zhang, Mingxing ;

Wang, Qian ;

Lu, Zhiyong ;

Liu, Huiyan ;

Liu, Wenlong ;

Bai, Junfeng .

CRYSTENGCOMM, 2014, 16 (28) :6287-6290

← 1 2 3 4 5 6 7 8 9 →