An amino-decorated NbO-type metal-organic framework for high C2H2 storage and selective CO2 capture

被引：50
作者：
Cai, Jianfeng [1 ]
Wang, Huizhen [1 ]
Wang, Hailong [2 ]
Duan, Xing [1 ]
Wang, Zhiyu [1 ]
Cui, Yuanjing [1 ]
Yang, Yu [1 ]
Chen, Banglin [1 ,2 ,3 ]
Qian, Guodong [1 ]
机构：
[1] Zhejiang Univ, Dept Mat Sci & Engn, Cyrus Tang Ctr Sensor Mat & Applicat, State Key Lab Silicon Mat, Hangzhou 310027, Zhejiang, Peoples R China
[2] Univ Texas San Antonio, Dept Chem, San Antonio, TX 78249 USA
[3] King Abdulaziz Univ, Dept Chem, Fac Sci, Jeddah 22254, Saudi Arabia
来源：
RSC ADVANCES | 2015年 / 5卷 / 94期
基金：
中国国家自然科学基金;
关键词：
CARBON-DIOXIDE CAPTURE; HIGH METHANE STORAGE; BASIC PYRIDYL SITES; HIGH ACETYLENE; HIGH-CAPACITY; ADSORPTIVE SEPARATION; HYDROGEN ADSORPTION; FUNCTIONAL-GROUPS; ACYLAMIDE GROUPS; H-2; ADSORPTION;
D O I：
10.1039/c5ra12700a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel amino-decorated NbO-type metal-organic framework [Cu-2(C22H11NO8)(H2O)(2)]center dot(DMF)(6)center dot(H2O), (ZJU-8, ZJU = Zhejiang University; DMF = N,N-dimethylformamide) has been synthesized and structurally characterized. The activated ZJU-8a exhibits both a high C2H2 uptake capacity (195 cm(3) g(-1) at 1 bar) and a moderately high adsorption selectivity for CO2 over N-2 (12.27) and CH4 (7.38) at room temperature.
引用
收藏
页码：77417 / 77422
页数：6
相关论文
共 86 条
[1]   Ligand design for functional metal-organic frameworks [J].
Almeida Paz, Filipe A. ;
Klinowski, Jacek ;
Vilela, Sergio M. F. ;
Tome, Joao P. C. ;
Cavaleiro, Jose A. S. ;
Rocha, Joao .
CHEMICAL SOCIETY REVIEWS, 2012, 41 (03) :1088-1110
[2]   Analysis of High and Selective Uptake of CO2 in an Oxamide-Containing {Cu2(OOCR)4}-Based Metal-Organic Framework [J].
Alsmail, Nada H. ;
Suyetin, Mikhail ;
Yan, Yong ;
Cabot, Rafel ;
Krap, Cristina P. ;
Lu, Jian ;
Easun, Timothy L. ;
Bichoutskaia, Elena ;
Lewis, William ;
Blake, Alexander J. ;
Schroeder, Martin .
CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (24) :7317-7324
[3]   Tuning MOF CO2 Adsorption Properties via Cation Exchange [J].
An, Jihyun ;
Rosi, Nathaniel L. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (16) :5578-+
[4]   High and Selective CO2 Uptake in a Cobalt Adeninate Metal-Organic Framework Exhibiting Pyrimidine- and Amino-Decorated Pores [J].
An, Jihyun ;
Geib, Steven J. ;
Rosi, Nathaniel L. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (01) :38-+
[5]   Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites [J].
Bloch, Eric D. ;
Queen, Wendy L. ;
Krishna, Rajamani ;
Zadrozny, Joseph M. ;
Brown, Craig M. ;
Long, Jeffrey R. .
SCIENCE, 2012, 335 (6076) :1606-1610
[6]   A NbO type microporous metal-organic framework constructed from a naphthalene derived ligand for CH4 and C2H2 storage at room temperature [J].
Cai, Jianfeng ;
Lin, Yichao ;
Yu, Jiancan ;
Wu, Chuande ;
Chen, Liang ;
Cui, Yuanjing ;
Yang, Yu ;
Chen, Banglin ;
Qian, Guodong .
RSC ADVANCES, 2014, 4 (90) :49457-49461
[7]   A highly porous NbO type metal-organic framework constructed from an expanded tetracarboxylate [J].
Cai, Jianfeng ;
Rao, Xingtang ;
He, Yabing ;
Yu, Jancan ;
Wu, Chuande ;
Zhou, Wei ;
Yildirim, Taner ;
Chen, Banglin ;
Qian, Guodong .
CHEMICAL COMMUNICATIONS, 2014, 50 (13) :1552-1554
[8]   A Doubly Interpenetrated Metal-Organic Framework with Open Metal Sites and Suitable Pore Sizes for Highly Selective Separation of Small Hydrocarbons at Room Temperature [J].
Cai, Jianfeng ;
Yu, Jiancan ;
Xu, Hui ;
He, Yabing ;
Duan, Xing ;
Cui, Yuanjing ;
Wu, Chuande ;
Chen, Banglin ;
Qian, Guodong .
CRYSTAL GROWTH & DESIGN, 2013, 13 (05) :2094-2097
[9]   Immobilization of Ag(I) into a metal-organic framework with -SO3H sites for highly selective olefin-paraffin separation at room temperature [J].
Chang, Ganggang ;
Huang, Minhui ;
Su, Ye ;
Xing, Huabin ;
Su, Baogen ;
Zhang, Zhiguo ;
Yang, Qiwei ;
Yang, Yiwen ;
Ren, Qilong ;
Bao, Zongbi ;
Chen, Banglin .
CHEMICAL COMMUNICATIONS, 2015, 51 (14) :2859-2862
[10]   Metal-Organic Frameworks with Functional Pores for Recognition of Small Molecules [J].
Chen, Banglin ;
Xiang, Shengchang ;
Qian, Guodong .
ACCOUNTS OF CHEMICAL RESEARCH, 2010, 43 (08) :1115-1124
123456789