A novel metal-organic framework based on bismuth and trimesic acid: synthesis, structure and properties

被引：110

作者：

Wang, Guanzhi ^{[1
]}

Liu, Yuanyuan ^{[1
]}

Huang, Baibiao ^{[1
]}

Qin, Xiaoyan ^{[1
]}

Zhang, Xiaoyang ^{[1
]}

Dai, Ying ^{[2
]}

机构：

[1] Shandong Univ, State Key Crystal Mat, Jinan 250100, Peoples R China

[2] Shandong Univ, Sch Phys, Jinan 250100, Peoples R China

来源：

DALTON TRANSACTIONS | 2015年 / 44卷 / 37期

基金：

中国国家自然科学基金;

关键词：

Organometallics - Crystalline materials;

D O I：

10.1039/c5dt03111g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A bismuth based metal-organic framework ([Bi(BTC)(DMF)]center dot DMF (CH3OH)(2), Bi-BTC) with a novel topology structure is synthesized by a solvothermal method. Bi-BTC crystalizes in the P2(1)/n space group, exhibits a novel 3D framework consisting of trimesic acid (H3BTC) linked with {Bi2O14} units and contains two helix chains which assemble regularly. In addition, we investigated the photophysical properties of Bi-BTC which shows high activity of O-2 production in photocatalysis.

引用

页码：16238 / 16241

页数：4