A novel metal-organic framework based on bismuth and trimesic acid: synthesis, structure and properties

被引：105
|
作者：
Wang, Guanzhi [1 ]
Liu, Yuanyuan [1 ]
Huang, Baibiao [1 ]
Qin, Xiaoyan [1 ]
Zhang, Xiaoyang [1 ]
Dai, Ying [2 ]
机构：
[1] Shandong Univ, State Key Crystal Mat, Jinan 250100, Peoples R China
[2] Shandong Univ, Sch Phys, Jinan 250100, Peoples R China
来源：
DALTON TRANSACTIONS | 2015年 / 44卷 / 37期
基金：
中国国家自然科学基金;
关键词：
High activity - Photophysical properties - Solvothermal method - Space Groups - Structure and properties - Topology structure - Trimesic acid;
D O I：
10.1039/c5dt03111g
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A bismuth based metal-organic framework ([Bi(BTC)(DMF)]center dot DMF (CH3OH)(2), Bi-BTC) with a novel topology structure is synthesized by a solvothermal method. Bi-BTC crystalizes in the P2(1)/n space group, exhibits a novel 3D framework consisting of trimesic acid (H3BTC) linked with {Bi2O14} units and contains two helix chains which assemble regularly. In addition, we investigated the photophysical properties of Bi-BTC which shows high activity of O-2 production in photocatalysis.
引用
收藏
页码：16238 / 16241
页数：4
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