Symmetric and non-symmetric bis-metallylene iron complexes, precursors of iron germanide nanoparticles

被引：8

作者：

Sodreau, Alexandre ^{[1
,2
]}

Lentz, Nicolas ^{[1
]}

Frutos, Maria ^{[1
]}

Mallet-Ladeira, Sonia ^{[3
]}

Nayral, Celine ^{[2
]}

Delpech, Fabien ^{[2
]}

Madec, David ^{[1
]}

机构：

[1] Univ Toulouse, CNRS, UMR 5069, Lab Heterochim Fondamentale & Appl, 118 Route Narbonne, F-31062 Toulouse, France

[2] Univ Toulouse, CNRS, INSA, LPCNO,UPS, 135 Ave Rangueil, F-31077 Toulouse, France

[3] Univ Paul Sabatier FR2599, Inst Chim Toulouse, 118 Route Narbonne, F-31062 Toulouse 09, France

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 64期

关键词：

N-HETEROCYCLIC GERMYLENES; LIGANDS SYNTHESES; SILYLENE; SILICON; DERIVATIVES; STANNYLENES; TIN; FE; GE;

D O I：

10.1039/c9cc05063a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report herein the synthesis of symmetric and non-symmetric bis-amidinato-germylene Fe(CO)(3) complexes, as well as the preparation of the corresponding disymmetric germylene-stannylene and germylene-silylene complexes by selective displacement of a carbonyl ligand under UV-a light irradiation. The symmetric bis-germylene Fe(CO)(3) complex has been applied in the synthesis of iron germanide nanocrystals.

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收藏

页码：9539 / 9542

页数：4

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