Anti-Markovnikov oxidation and hydration of terminal olefins

被引：48

作者：

Guo, Jiayi ^{[1
]}

Teo, Peili ^{[1
,2
]}

机构：

[1] Natl Univ Singapore, Dept Chem, S-117543 Singapore, Singapore

[2] Inst Chem & Engn Sci, S-627833 Singapore, Singapore

来源：

DALTON TRANSACTIONS | 2014年 / 43卷 / 19期

关键词：

WACKER-TYPE OXIDATION; PALLADIUM-CATALYZED SYNTHESIS; PROTECTED ALLYLIC AMINES; RH/RU DUAL CATALYST; TANDEM HYDROFORMYLATION/HYDROGENATION; AEROBIC OXIDATION; PRIMARY ALCOHOLS; ALKENES; ALDEHYDES; COMPLEXES;

D O I：

10.1039/c3dt53600a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Efficient syntheses of aldehydes and primary alcohols from terminal olefins are critical to the chemical laboratory and industry. Heavy emphasis has been placed on regioselective olefin functionalization in recent decades. This perspective mainly focuses on advances in the Wacker-type oxidation and tandem hydration of terminal olefins with anti-Markovnikov selectivity.

引用

页码：6952 / 6964

页数：13

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