Oxidative and anaerobic reactions of benzyl alcohol catalysed by a Pd-561 giant cluster

被引：14

作者：

Hladyi, SS

Starchevsky, MK ^{[1
]}

Pazdersky, YA

Vargaftik, MN

Moiseev, II

机构：

[1] Sintez Res Inst, UA-82300 Borislav, Ukraine

[2] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

来源：

MENDELEEV COMMUNICATIONS | 2002年 / 02期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1070/MC2002v012n02ABEH001568

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The unusual redox disproportionation of benzyl alcohol to benzaldehyde and toluene catalysed by the Pd(561)phen(60)(OAc)(180) giant cluster under anaerobic conditions was found, whereas in an O-2 atmosphere the Pd giant cluster catalyses benzyl alcohol oxidation to benzaldehyde and inhibits its further oxidation.

引用

页码：45 / 46

页数：2

共 6 条

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[2]

Moiseev II, 1998, CHEM MET CLUST, P395

[3]

Starchevskii MK, 1996, KINET CATAL+, V37, P383

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Moiseev, II .

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[5]

STARCHEVSKY MK, 1995, DOKL CHEM, V342, P157

[6] GIANT PALLADIUM CLUSTERS AS CATALYSTS OF OXIDATIVE REACTIONS OF OLEFINS AND ALCOHOLS [J].

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MOISEEV, II ;

KOCHUBEY, DI ;

LIKHOLOBOV, VA ;

CHUVILIN, AL ;

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