The film deposition via atmospheric pressure plasma from ethanol and He mixing gases

被引:12
作者
Chen, Ko-Shao [1 ]
Liao, Shu-Chuan [1 ,4 ]
Lin, Shen-Wei [1 ]
Tsao, Shao-Hsuan [1 ]
Ting, Tsai Hsin [1 ]
Inagaki, Norihiro [2 ]
Wu, Hsin-Ming [1 ]
Chen, Wei-Yu [3 ]
机构
[1] Tatung Univ, Dept Mat Engn, Taipei 104, Taiwan
[2] Shizuoka Univ, Fac Engn, Shizuoka 4228529, Japan
[3] Natl Taiwan Univ, Inst Biomed Engn, Taipei 10764, Taiwan
[4] Ming Chi Univ Technol, Ctr Thin Film Technol & Applicat, New Taipei City, Taiwan
关键词
APPD; Plasma films; Ethanol; Surface graft; NIPAAm; SURFACE MODIFICATION;
D O I
10.1016/j.surfcoat.2012.06.064
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In this study, using atmospheric pressure plasma deposition (APPD) treated surface of mixing He gas and ethanol to deposit organic and hydrophilic thin film on glass or polyethylene terephthalate (PET) substrates. Formed peroxide groups in surface by APPD coating which are favorable to surface graft polymerization of thermo-sensitive monomer N-isopropylacrylamide (NIPAAm) on the surface. NIPAAm has specific thermo-sensitive property. The results show that after the plasma treatment, new oxygen-containing polar groups such as C-O and O-C=O are generated on the slide glass, and the wettability of substrate is greatly change to hydrophilic. The water contact angle of slide glass or PET surface decreases from 70 degrees Delta +/- 1 to 23 degrees Delta +/- 1 after plasma treatment. While slide glass grafted NIPAAm in wet state would change from colorless to white as temperature higher than lower critical solution temperature (LCST) is 33 degrees C. Crown Copyright (C) 2012 Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:408 / 411
页数:4
相关论文
共 10 条
  • [1] Surface grafting of a thermoplastic polyurethane with methacrylic acid by previous plasma surface activation and by ultraviolet irradiation to reduce cell adhesion
    Alves, P.
    Pinto, S.
    Kaiser, Jean-Pierre
    Bruinink, Arie
    de Sousa, Herminio C.
    Gil, M. H.
    [J]. COLLOIDS AND SURFACES B-BIOINTERFACES, 2011, 82 (02) : 371 - 377
  • [2] Surface modification and characterization of thermoplastic polyurethane
    Alves, P.
    Coelho, J. F. J.
    Haack, Janne
    Rota, Astrid
    Bruinink, Arie
    Gil, M. H.
    [J]. EUROPEAN POLYMER JOURNAL, 2009, 45 (05) : 1412 - 1419
  • [3] Effects of additives on the photo-induced grafting polymerization of N-isopropylacrylamide gel onto PET film and PP nonwoven fabric surface
    Chen, KS
    Rsai, JC
    Chou, CW
    Yang, MR
    Yang, JM
    [J]. MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS, 2002, 20 (1-2): : 203 - 208
  • [4] Preparation and characterization of coaxial electrospun thermoplastic polyurethane/collagen compound nanofibers for tissue engineering applications
    Chen, Rui
    Huang, Chen
    Ke, Qinfei
    He, Chuanglong
    Wang, Hongsheng
    Mo, Xiumei
    [J]. COLLOIDS AND SURFACES B-BIOINTERFACES, 2010, 79 (02) : 315 - 325
  • [5] Surface Modification of Nylon 6 Films Treated with an He/O2 Atmospheric Pressure Plasma Jet
    Gao, Zhiqiang
    Sun, Jie
    Peng, Shujing
    Yao, Lan
    Qiu, Yiping
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2011, 120 (04) : 2201 - 2206
  • [6] Atmospheric-pressure plasma treatment on polystyrene for the photo-induced grafting polymerization of N-isopropylacrylamide
    Kuo, Yu-Lin
    Chang, Kuang-Hui
    Hung, Tusi-Shan
    Chen, Ko-Shao
    Inagaki, Norihiro
    [J]. THIN SOLID FILMS, 2010, 518 (24) : 7568 - 7573
  • [7] Morshedian J, 2005, IRAN POLYM J, V14, P139
  • [8] Nanci A, 1998, J BIOMED MATER RES, V40, P324
  • [9] Mechanical behavior of electrospun polyurethane
    Pedicini, A
    Farris, RJ
    [J]. POLYMER, 2003, 44 (22) : 6857 - 6862
  • [10] Wettability and lubrication of polytetrafluorethylene (PTFE) by UV-induced graft copolymerization on plasma-treated surface
    Yang, MR
    Chen, KS
    [J]. MATERIALS CHEMISTRY AND PHYSICS, 1997, 50 (01) : 11 - 14