Nitroxide-catalyzed transition-metal-free aerobic oxidation processes

被引：287
|
作者：
Wertz, Sebastian [1 ]
Studer, Armido [1 ]
机构：
[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany
来源：
GREEN CHEMISTRY | 2013年 / 15卷 / 11期
关键词：
N-HYDROXYPHTHALIMIDE NHPI; MOLECULE-INDUCED HOMOLYSIS; BAEYER-VILLIGER OXIDATION; TERTIARY ALLYLIC ALCOHOLS; ELECTRON-TRANSFER; HIGHLY EFFICIENT; SELECTIVE OXIDATION; BENZYLIC ALCOHOLS; MILD CONDITIONS; SOLVENT-FREE;
D O I：
10.1039/c3gc41459k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Advances in the field of transition-metal-free nitroxide-catalyzed aerobic oxidation processes are covered in this critical review. Along with the relevant physical properties of nitroxides, their application as oxidation catalysts by using dioxygen as a reagent or terminal oxidant will be discussed. The second part of the review focuses on the use of TEMPO-based nitroxides as catalysts for aerobic alcohol oxidation. Mechanistic studies will also be addressed (130 references).
引用
收藏
页码：3116 / 3134
页数：19
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