Quantum-confined GaN nanoparticles synthesized via liquid-ammonia-in-oil-microemulsions

被引：13

作者：

Gyger, Fabian ^{[1
]}

Bockstaller, Pascal ^{[2
]}

Groeger, Henriette ^{[1
]}

Gerthsen, Dagmar ^{[2
]}

Feldmann, Claus ^{[1
]}

机构：

[1] Karlsruhe Inst Technol, Inst Anorgan Chem, D-76131 Karlsruhe, Germany

[2] Karlsruhe Inst Technol, Lab Elektronenmikroskopie, D-76131 Karlsruhe, Germany

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 22期

关键词：

GALLIUM NITRIDE; METATHESIS ROUTE; DOTS; CHEMISTRY;

D O I：

10.1039/c4cc00180j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

GaN nanoparticles, 3-4 nm in size, are synthesized in a microemulsion using liquid ammonia as the polar droplet phase. Surprisingly, GaN is readily crystalline although prepared at -40 degrees C. The nanoparticles show a band gap of 4.4 eV as well as light emission with its maximum at 336 nm. Both confirm the expected quantum-confinement effect.

引用

页码：2939 / 2942

页数：4

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