Improving the Hydrogen-Adsorption Properties of a Hydroxy-Modified MIL-53(Al) Structural Analogue by Lithium Doping

被引：188
作者：
Himsl, Dieter [1 ]
Wallacher, Dirk [2 ]
Hartmann, Martin [1 ]
机构：
[1] Univ Augsburg, Inst Phys, D-86159 Augsburg, Germany
[2] Helmholtz Zentrum Mat & Energie GmbH, D-14109 Berlin, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 25期
关键词：
adsorption; doping; hydrogen; lithium; microporous materials; METAL-ORGANIC FRAMEWORKS; HETEROGENEOUS ASYMMETRIC CATALYSIS; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; MAGNETIC-PROPERTIES; STORAGE CAPACITY; SALICYLIC-ACID; SURFACE-AREA; H-2; STORAGE; FUNCTIONALIZATION;
D O I：
10.1002/anie.200806203
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Lithium makes the difference: A simple strategy for the synthesis of lithium-doped porous metal-organic frameworks (MOFs) is developed (see structure; C black, O red, AlO6 blue octahedra), thus paving the way for the facile preparation of lithium-doped MOFs. Moreover, the significant increase in hydrogen adsorption predicted by theoretical calculations is observed. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：4639 / 4642
页数：4
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