Growth Mechanism of Metal-Organic Frameworks: Insights into the Nucleation by Employing a Step-by-Step Route

被引：349

作者：

Shekhah, Osama ^{[1
]}

Wang, Hui ^{[1
]}

Zacher, Denise ^{[1
]}

Fischer, Roland A. ^{[1
]}

Woell, Christof ^{[1
]}

机构：

[1] Ruhr Univ Bochum, D-44801 Bochum, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 27期

关键词：

mechanistic studies; metal-organic frameworks; monolayers; nucleation; secondary building blocks; SELF-ASSEMBLED MONOLAYERS; POROUS COORDINATION POLYMERS; FORCE MICROSCOPY; SURFACE; CARBOXYLATE; FABRICATION;

D O I：

10.1002/anie.200900378

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

One step at a time: The in situ monitoring of the step-bystep formation of metal-organic frameworks (MOFs) by using surface plasmon resonance (SPR), allows the nucleation process and the formation of the secondary building units to be investigated. Growth rates on functionalized organic surfaces with different crystallographic orientations can also be studied. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

收藏

页码：5038 / 5041

页数：4

相关论文

共 35 条

[1] Preparation, modification, and crystallinity of aliphatic and aromatic carboxylic acid terminated self-assembled monolayers [J].

Arnold, R ;

Azzam, W ;

Terfort, A ;

Wöll, C .

LANGMUIR, 2002, 18 (10) :3980-3992

[2] Functional porous material - MOFs - Metal organic frame structure [J].

Bauer, Sebastian ;

Stock, Norbert .

CHEMIE IN UNSERER ZEIT, 2008, 42 (01) :12-19

[3] Oriented growth of the metal organic framework Cu3(BTC)2(H2O)3•xH2O tunable with functionalized self-assembled monolayers [J].

Biemmi, Enrica ;

Scherb, Camilla ;

Bein, Thomas .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (26) :8054-+

[4] Structural diversity and chemical trends in hybrid inorganic-organic framework materials [J].

Cheetham, Anthony K. ;

Rao, C. N. R. ;

Feller, Russell K. .

CHEMICAL COMMUNICATIONS, 2006, (46) :4780-4795

[5] Microporous solids:: From organically templated inorganic skeletons to hybrid frameworks ... ecumenism in chemistry [J].

Férey, G .

CHEMISTRY OF MATERIALS, 2001, 13 (10) :3084-3098

[6]

Furukawa S., 2009, Angewandte Chemie, V121, P1798, DOI DOI 10.1002/ANGE.200804836

[7] Heterogeneously Hybridized Porous Coordination Polymer Crystals: Fabrication of Heterometallic Core-Shell Single Crystals with an In-Plane Rotational Epitaxial Relationship [J].

Furukawa, Shuhei ;

Hirai, Kenji ;

Nakagawa, Keiji ;

Takashima, Yohei ;

Matsuda, Ryotaro ;

Tsuruoka, Takaaki ;

Kondo, Mio ;

Haruki, Rie ;

Tanaka, Daisuke ;

Sakamoto, Hirotoshi ;

Shimomura, Satoru ;

Sakata, Osami ;

Kitagawa, Susumu .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (10) :1766-1770

[8] Selective nucleation and growth of metal-organic open framework thin films on patterned COOH/CF3-terminated self-assembled monolayers on Au(111) [J].

Hermes, S ;

Schröder, F ;

Chelmowski, R ;

Wöll, C ;

Fischer, RA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (40) :13744-13745

[9] Metal@MOF:: Loading of highly porous coordination polymers host lattices by metal organic chemical vapor deposition [J].

Hermes, S ;

Schröter, MK ;

Schmid, R ;

Khodeir, L ;

Muhler, M ;

Tissler, A ;

Fischer, RW ;

Fischer, RA .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (38) :6237-6241

[10]

Hermes S., 2005, Angew. Chem, V117, P6394

← 1 2 3 4 →