An ultrastable, flexible POM-based coordination polymer with redox properties

被引：14

作者：

Luo, Yu-Hui ^{[1
]}

Lu, Xin-Xin ^{[1
]}

Zhang, Hong ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Jilin, Peoples R China

来源：

CRYSTENGCOMM | 2014年 / 16卷 / 34期

关键词：

METAL-ORGANIC FRAMEWORK; BILAYER OPEN FRAMEWORK; POLYOXOMETALATE; LUMINESCENCE; ADSORPTION; SEPARATION; STABILITY; CHEMISTRY; MIL-53; ANION;

D O I：

10.1039/c4ce01123f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new flexible coordination polymer based on the Keggin-type structure H3PW12O40 center dot xH(2)O, [Cu(L)(2)(H2O)H(PW12O40)]center dot 7H(2)O (1), has been prepared. The framework of 1 shows dynamic behavior accompanied with the removal/adsorption of guest water molecules. Compound 1 can remain intact even in 8 mol L-1 hydrochloric acid, dilute NaOH solution (pH = 12) and boiling water.

引用

页码：7865 / 7868

页数：4

共 56 条

[1] Diphosphates and diphosphonates in polyoxometalate chemistry [J].

Banerjee, Abhishek ;

Bassil, Bassem S. ;

Roeschenthaler, Gerd-Volker ;

Kortz, Ulrich .

CHEMICAL SOCIETY REVIEWS, 2012, 41 (22) :7590-7604

[2]

Biradha K, 2002, ANGEW CHEM INT EDIT, V41, P3395, DOI 10.1002/1521-3773(20020916)41:18<3395::AID-ANIE3395>3.0.CO

[3]

2-D

[4] Elucidating the Breathing of the Metal-Organic Framework MIL-53(Sc) with ab Initio Molecular Dynamics Simulations and in Situ X-ray Powder Diffraction Experiments [J].

Chen, Linjiang ;

Mowat, John P. S. ;

Fairen-Jimenez, David ;

Morrison, Carole A. ;

Thompson, Stephen P. ;

Wright, Paul A. ;

Dueren, Tina .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (42) :15763-15773

[5] Dynamic and redox active pillared bilayer open framework: Single-crystal-to-single-crystal transformations upon guest removal, guest exchange, and framework oxidation [J].

Choi, HJ ;

Suh, MP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (48) :15844-15851

[6] High thermal and chemical stability in pyrazolate-bridged metal-organic frameworks with exposed metal sites [J].

Colombo, Valentina ;

Galli, Simona ;

Choi, Hye Jin ;

Han, Ggoch Ddeul ;

Maspero, Angelo ;

Palmisano, Giovanni ;

Masciocchi, Norberto ;

Long, Jeffrey R. .

CHEMICAL SCIENCE, 2011, 2 (07) :1311-1319

[7] From serendipity to design of polyoxometalates at the nanoscale, aesthetic beauty and applications [J].

Cronin, Leroy ;

Mueller, Achim .

CHEMICAL SOCIETY REVIEWS, 2012, 41 (22) :7333-7334

[8] A 3D all-inorganic architecture based on the [H2W12O42]10- building block with different alkaline-earth metal linkers: crystal structures, surface photovoltage and photoluminescent properties [J].

Cui, Keyu ;

Li, Fengyan ;

Xu, Lin ;

Wang, Yuchao ;

Sun, Zhixia ;

Fu, Honggang .

CRYSTENGCOMM, 2013, 15 (23) :4721-4729

[9] Using Functional Nano- and Microparticles for the Preparation of Metal-Organic Framework Composites with Novel Properties [J].

Doherty, Cara M. ;

Buso, Dario ;

Hill, Anita J. ;

Furukawa, Shuhei ;

Kitagawa, Susumu ;

Falcaro, Paolo .

ACCOUNTS OF CHEMICAL RESEARCH, 2014, 47 (02) :396-405

[10] Hydrothermal synthesis and crystal structure of a novel Keggin polyoxoanion-templated multichain coordination polymer with a flexible bis(imidazole) ligand [J].

Dong, Baoxia ;

Peng, Jun ;

Zhang, Pengpeng ;

Tian, Aixiang ;

Chen, Jing ;

Xue, Bo .

INORGANIC CHEMISTRY COMMUNICATIONS, 2007, 10 (07) :839-842

← 1 2 3 4 5 6 →