Effect of hydrogen redistribution during aging on the structure and phase state of nanocrystalline and coarse-grained TiNi alloys

被引:15
作者
Baturin, Anatoly [1 ,2 ]
Lotkov, Aleksander [1 ]
Grishkov, Victor [1 ]
Rodionov, Ivan [1 ]
Kudiiarov, Victor [2 ]
机构
[1] RAS, Inst Strength Phys & Mat Sci, SB, 2-4 Pr Akad Skii, Tomsk 634055, Russia
[2] Tomsk Polytech Univ, 30 Lenin Ave, Tomsk 634055, Russia
基金
俄罗斯基础研究基金会;
关键词
TiNi alloy; Hydrogen; Aging; Martensite transformation; DSC; Nanocrystalline and coarse-grained structure; EMBRITTLEMENT;
D O I
10.1016/j.jallcom.2018.04.045
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The report presents research data showing how the phase state and transition temperatures in hydrogenated nanocrystalline and coarse-grained TiNi alloys are influenced by hydrogen redistribution on their aging at room temperature. The research methods include four-point measurements of resistivity as a function of temperature and differential scanning calorimetry at 173-373 K. The results demonstrate that hydrogen diffusion in the material bulk provides gradual suppression of B2 -> B19' and R -> B19' transformations and that the temperature of B2 -> R transformation is hardy sensitive to hydrogen. Also presented is an analysis of the mechanism by which hydrogen acts on the temperatures and sequence of martensite transformations. (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码:359 / 363
页数:5
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