Acceptorless Dehydrogenation of Alcohols Catalyzed by CuI N-Heterocycle Thiolate Complexes

被引：37

作者：

Tan, Da-Wei ^{[1
]}

Li, Hong-Xi ^{[1
,2
]}

Zhang, Meng-Juan ^{[1
]}

Yao, Jian-Lin ^{[1
]}

Lang, Jian-Ping ^{[1
,3
]}

机构：

[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, State & Local Joint Engn Lab Novel Funct Polymer, Suzhou 215123, Peoples R China

[2] Soochow Univ, Appl Technol Coll, Suzhou 215325, Peoples R China

[3] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

CHEMCATCHEM | 2017年 / 9卷 / 06期

基金：

中国国家自然科学基金;

关键词：

alcohols; cluster compounds; copper; dehydrogenation; heterocycles; OXIDANT-FREE DEHYDROGENATION; ASYMMETRIC CONJUGATE ADDITION; AEROBIC OXIDATION CATALYSIS; SECONDARY BENZYLIC ALCOHOLS; PRIMARY ALIPHATIC-ALCOHOLS; SUPPORTED COPPER CATALYST; HETEROGENEOUS CATALYSIS; TRANSFER HYDROGENATION; RUTHENIUM CATALYSTS; BORROWING HYDROGEN;

D O I：

10.1002/cctc.201601459

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Cu-I N-heterocycle thiolate clusters efficiently catalyze the acceptorless dehydrogenation of alcohols at 70 degrees C. A variety of secondary/primary benzylic, allylic, and aliphatic alcohols are dehydrogenated to the corresponding ketones and aldehydes in high yields of isolated product upon release of H-2. This simple catalytic system is involved in the synthesis of imines through the one-pot reaction of alcohols and amines.

引用

页码：1113 / 1118

页数：6

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