Facile Synthesis of Anatase TiO2 Quantum- Dot/GrapheneNanosheet Composites with Enhanced Electrochemical Performance for Lithium-Ion Batteries

被引:288
作者
Mo, Runwei [1 ]
Lei, Zhengyu [1 ]
Sun, Kening [1 ]
Rooney, David [2 ]
机构
[1] Harbin Inst Technol, Acad Fundamental & Interdisciplinary Sci, Harbin 150001, Peoples R China
[2] Queens Univ Belfast, Sch Chem & Chem Engn, Belfast BT9 5AG, Antrim, North Ireland
基金
中国国家自然科学基金;
关键词
emulsion technique; TiO2 quantum dots; graphene; lithium-ion batteries; HIGH-CAPACITY; ELECTRODE MATERIALS; CATHODE MATERIAL; ANODE MATERIALS; NANOSHEETS; INSERTION; STORAGE; TIO2-GRAPHENE; FABRICATION; GRAPHITE;
D O I
10.1002/adma.201304338
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A facile method to synthesize well-dispersed TiO2 quantum dots on graphene nanosheets (TiO2-QDs/GNs) in a water-in-oil (W/O) emulsion system is reported. The TiO2/graphene composites display high performance as an anode material for lithium-ion batteries (LIBs), such as having high reversible lithium storage capacity, high Coulombic efficiency, excellent cycling stability, and high rate capability. The excellent electrochemical performance and special structure of the composites thus offer a way to prepare novel graphene-based electrode materials for high-energy-density and high-power LIBs. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:2084 / 2088
页数:5
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