Structural, Optical, and Isothermic Studies of CuFe2O4 and Zn-Doped CuFe2O4 Nanoferrite as a Magnetic Catalyst for Photocatalytic Degradation of Direct Red 264 Under Visible Light Irradiation

被引:22
作者
Kar, Mahnaz Kamel Attar [1 ]
Fazaeli, Reza [2 ]
Manteghi, Faranak [1 ]
Ghahari, Mahdi [3 ]
机构
[1] Iran Univ Sci & Technol, Dept Chem, Tehran, Iran
[2] Islamic Azad Univ, South Tehran Branch, Fac Engn, Dept Chem Engn, Tehran, Iran
[3] Inst Color Sci & Technol, Nanocoating & Nanomat Dept, Tehran, Iran
关键词
copper nanoferrites; band gap energy; photocatalytic degradation; DR; 264; AZO-DYE; FERRITE NANOPARTICLES; AQUEOUS-SOLUTIONS; COPPER FERRITE; ADSORPTION; REMOVAL; SYSTEM; NI; CU;
D O I
10.1002/ep.13109
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Cu and Zn-doped Cu ferrites were synthesized by sol-gel auto-combustion method. The samples were characterized by XRD, SEM, EDX, VSM, FT-IR, and DRS methods. Powder XRD analysis and FT-IR spectroscopy confirmed the formation of ferrites spinel phase. The crystallite sizes were calculated using Scherrer's equation. The morphologies and sizes of the synthesized nanoparticles have been observed by scanning electron microscopy. The saturation magnetization (MS) is obtained from VSM data. The energy band gaps were calculated from UV-DRS absorption data. Removal of Direct Red 264 was carried out by CuFe2O4 and Zn-doped CuFe2O4 as catalysts under a visible lamp. The kinetic and isothermic analysis of photocatalytic degradation was studied. (c) 2019 American Institute of Chemical Engineers Environ Prog, 38:e13109, 2019
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页数:11
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