Metallic Nanoparticles in Heterogeneous Catalysis

被引：76

作者：

Sapi, Andras ^{[1
]}

Rajkumar, T. ^{[1
]}

Kiss, Janos ^{[1
,2
]}

Kukovecz, Akos ^{[1
]}

Konya, Zoltan ^{[1
,2
]}

Somorjai, Gabor A. ^{[3
]}

机构：

[1] Univ Szeged, Dept Appl & Environm Chem, Interdisciplinary Excellence Ctr, Rerrich Bela Ter 1, H-6720 Szeged, Hungary

[2] MTA SZTE React Kinet & Surface Chem Res Grp, Rerrich Bela Ter 1, H-6720 Szeged, Hungary

[3] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

CATALYSIS LETTERS | 2021年 / 151卷 / 08期

关键词：

Metallic nanoparticles; Core-shell nanoparticles; In-situ techniques; Single atom catalysis; FISCHER-TROPSCH CATALYSTS; CATALYTICALLY ACTIVE GOLD; COBALT PARTICLE-SIZE; CO OXIDATION; IN-SITU; CARBON-MONOXIDE; SUPPORT INTERACTIONS; STRUCTURE SENSITIVITY; ELECTRONIC-STRUCTURE; BIMETALLIC CLUSTERS;

D O I：

10.1007/s10562-020-03477-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Heterogeneous catalysis is a chemical process achieved at solid-gas or solid-liquid interfaces. Many factors including the particle size, shape and metal-support interfaces can have significant influences on the catalytic properties of metal catalysts. The recent progress in the synthesis techniques and advanced characterization tools allow to understand the catalytic mechanisms at molecular level. In this Review, the size and shape dependent catalytic chemistry of metal nanoparticles and their electronic properties will be discussed. Then the unique catalytic chemistry at the metal-support interfaces will be discussed in details. Furthermore, the challenges of bimetallic nanoparticle catalytic chemistry will be discussed.

引用

页码：2153 / 2175

页数：23