Transient operation of a catalytic liquid-liquid plug flow reactor for kinetics measurements

被引：6
作者：
Caravieilhes, S [1 ]
Schweich, D [1 ]
de Bellefon, C [1 ]
机构：
[1] CNRS, Lab Genie Procedes Catalyt, ESCPE Lyon, CPE Lyon, F-69616 Villeurbanne, France
来源：
CHEMICAL ENGINEERING SCIENCE | 2002年 / 57卷 / 14期
关键词：
molecular catalysis; kinetics; liquid-liquid partition; chromatographic reactor; transient response; mass transfer;
D O I：
10.1016/S0009-2509(02)00143-4
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
A centrifugal partition chromatograph (CPC) was used as a liquid-liquid catalytic reactor for the isomerisation of hexen-3-ol into ethylpropylketone with a water soluble rhodium catalyst. Global mass transfer coefficients were measured and shown to depend on both the nature of the solute and the flow rate. Liquid-liquid partition isotherms were also determined with the CPC using elution chromatography. Finally, a reactor model was derived to account for the experimental results obtained both under stationary and transient (pulse) conditions. A parameter sensitivity evaluation is also presented. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：2697 / 2705
页数：9
相关论文
共 29 条
[1]  
BAERNS M, 1996, APPL HOMOGENEOUS CAT, V2, P686
[2]  
CARAVIEIHES S, 2001, CATAL TODAY, V66, P15
[3]   Dynamic methods and new reactors for liquid phase molecular catalysis [J].
Caravieilhes, S ;
de Bellefon, C ;
Tanchoux, N .
CATALYSIS TODAY, 2001, 66 (2-4) :145-155
[4]  
CARAVIEILHES S, 2000, THESIS U C BERNARD L
[5]   INTRODUCING TPPTS AND RELATED LIGANDS FOR INDUSTRIAL BIPHASIC PROCESSES [J].
CORNILS, B ;
KUNTZ, EG .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 502 (1-2) :177-186
[6]   New reactors and methods for the investigation of homogeneous catalysis [J].
de Bellefon, C ;
Tanchoux, N ;
Caravieilhes, S .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 567 (1-2) :143-150
[7]   Concomitant use of liquid-liquid batch and continuous plug flow reactors for kinetic model discrimination. Application to the Rh/TPPTS catalysed reduction of the C-C double bond in dimethylitaconate [J].
de Bellefon, C ;
Tanchoux, N ;
Caravieilhes, S ;
Schweich, D .
CATALYSIS TODAY, 1999, 48 (1-4) :211-219
[8]   Efficient catalytic isomerization of allylic alcohols to carbonyl compounds with water soluble rhodium complexes [J].
de Bellefon, C ;
Caravieilhes, S ;
Kuntz, EG .
COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE, 2000, 3 (07) :607-614
[9]   A liquid-liquid plug flow continuous reactor for the investigation of catalytic reactions: The centrifugal partition chromatograph [J].
de Bellefon, C ;
Caravieilhes, S ;
Joly-Vuillemin, C ;
Schweich, D ;
Berthod, A .
CHEMICAL ENGINEERING SCIENCE, 1998, 53 (01) :71-74
[10]  
DEBELLEFON C, 2000, COMPTES RENDUS 1 A C, V2, P607
123