Synthesis of Novel Indazole-Derived Ionic Liquids

被引:5
|
作者
Palit, Subhadeep [1 ]
Bera, Smritilekha [1 ]
Singh, Man [1 ]
Mondal, Dhananjoy [1 ]
机构
[1] Cent Univ Gujarat, Sch Chem Sci, Gandhinagar 382030, India
来源
SYNTHESIS-STUTTGART | 2015年 / 47卷 / 21期
关键词
indazole; ionic liquids; green solvents; Meerwein's salts; physicochemical properties; ACID; IMIDAZOLIUM; DERIVATIVES; SOLVENTS; AGONIST; DESIGN;
D O I
10.1055/s-0034-1381135
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A very simple, convenient, two-step halide-free method for the synthesis of a novel homologous series of 36 room-temperature indazolium ionic liquids is reported, in which the indazolium moiety is substituted with different n-alkyl chains, and coupled with a tetrafluoroborate anion. As an example, the newly designed indazolium ionic liquid, 1-ethyl-2-pentyl-2H-indazol-2-ium tetrafluoroborate ([EPentIn]BF4) is employed as an ionic solvent to demonstrate its efficiency as a green solvent in a crossed aldol condensation reaction.
引用
收藏
页码:3371 / 3384
页数:14
相关论文
共 50 条
  • [1] Novel L-Tartaric Acid Derived Pyrrolidinium Cations for the Synthesis of Chiral Ionic Liquids
    Bonanni, Marco
    Soldaini, Gianluca
    Faggi, Cristina
    Goti, Andrea
    Cardona, Francesca
    SYNLETT, 2009, (05) : 747 - 750
  • [2] Exploration of Indazole-Derived Oxadiazoles and Thiadiazoles as Potential Antimycobacterial Agents: Synthesis and In Silico Docking Analysis
    V. S. R. Avuthu
    A. B. Reddy
    A. R. Basireddy
    P. R. Patel
    M. N. Ganivada
    P. V. V. N. Kishore
    Russian Journal of Bioorganic Chemistry, 2025, 51 (2) : 584 - 600
  • [3] Synthesis of novel functional ionic liquids and their application in biomass
    Han, Hui-Ying
    Geng, Xin
    Zhang, Bi-Xian
    Meng, Jing
    Liu, Xin
    He, Xin-Miao
    Liu, Zi-Guang
    Gao, Yun-Fei
    Liu, Di
    Hu, Xiao-Mei
    RSC ADVANCES, 2019, 9 (51) : 29652 - 29658
  • [4] Novel Type of α-Amino Acid Derived Imidazolium Ionic Liquids
    Marek, Ales
    Bures, Filip
    Kulhanek, Jiri
    SYNTHESIS-STUTTGART, 2014, 46 (21): : 2937 - 2944
  • [5] Synthesis and characterisation of novel nopyl-derived phosphonium ionic liquids
    Yu, Jiangou
    Wheelhouse, Richard T.
    Honey, Mark A.
    Karodia, Nazira
    JOURNAL OF MOLECULAR LIQUIDS, 2020, 316
  • [6] Dimethylthioformamide-derived ionic liquids: Synthesis, characterization and application as supercapacitor electrolyte
    Kong, Jing
    Liu, Lingwen
    Li, Xuan
    Yang, Yue
    Chen, Xiaoxin
    Fei, Yuqing
    Xu, Lin
    Chen, Zhengjian
    JOURNAL OF MOLECULAR LIQUIDS, 2022, 365
  • [7] Synthesis and characterization of new functionalized ionic liquids: Anticancer, cheminformatics and modeling studies
    Almutairi, Saud M.
    Messali, Mouslim
    Sahu, Pramod K.
    Bardaweel, Sanaa K.
    Rezki, Nadjet
    Aouad, Mohamed Reda
    Ali, Salim
    Malik, Azam
    Ali, Imran
    MOROCCAN JOURNAL OF CHEMISTRY, 2025, 13 (02): : 581 - 597
  • [8] Recent Advances in the Synthesis and Applications of Ionic Liquids Derived from Natural Products
    Khorasani, Fereshteh
    Ranjbar-Karimi, Reza
    Marra, Alberto
    SYNTHESIS-STUTTGART, 2024, 56 (23): : 3519 - 3542
  • [9] In Silica HTS and Structure Based Optimization of Indazole-Derived ULK1 Inhibitors
    Wood, Spencer D.
    Grant, Wayne
    Adrados, Isabel
    Choi, Jun Yong
    Alburger, James M.
    Duckett, Derek R.
    Roush, William R.
    ACS MEDICINAL CHEMISTRY LETTERS, 2017, 8 (12): : 1258 - 1263
  • [10] Mandelic acid derived ionic liquids: synthesis, toxicity and biodegradability
    Prydderch, Hannah
    Haiss, Annette
    Spulak, Marcel
    Quilty, Brid
    Kuemmerer, Klaus
    Heise, Andreas
    Gathergood, Nicholas
    RSC ADVANCES, 2017, 7 (04) : 2115 - 2126