A new class of bipyrimidine-based octupolar chromophores: synthesis, fluorescent and quadratic nonlinear optical properties

被引：46
作者：
Akdas-Kilig, Huriye [1 ]
Roisnel, Thierry [1 ]
Ledoux, Isabelle [2 ]
Le Bozec, Hubert [1 ]
机构：
[1] Univ Rennes 1, CNRS, UMR 6226, F-35042 Rennes, France
[2] ENS Cachan, Inst Alembert, CNRS, Lab Photon Quant & Mol,UMR 8537, F-94235 Cachan, France
来源：
NEW JOURNAL OF CHEMISTRY | 2009年 / 33卷 / 07期
关键词：
CHARGE-TRANSFER; 2ND-ORDER POLARIZABILITY; 1ST HYPERPOLARIZABILITY; NONDIPOLAR STRUCTURES; THREEFOLD SYMMETRY; HIGHLY EFFICIENT; MOLECULES; COMPLEXES; CRYSTAL; DERIVATIVES;
D O I：
10.1039/b907323j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
New D-2d octupolar organic chromophores based on bipyrimidine as a strong acceptor group exhibit strong fluorescence, fluorosolvatochromism and large second-order nonlinear optical responses.
引用
收藏
页码：1470 / 1473
页数：4
相关论文
共 59 条
[1]   Bis- and tris(arylethynyl)pyrimidine oligomers:: synthesis and light-emitting properties [J].
Achelle, Sylvain ;
Ramondenc, Yvan ;
Dupas, Georges ;
Ple, Nelly .
TETRAHEDRON, 2008, 64 (12) :2783-2791
[2]   Improved transparency-nonlinearity trade-off with boroxine-based octupolar molecules [J].
Alcaraz, G ;
Euzenat, L ;
Mongin, O ;
Katan, C ;
Ledoux, I ;
Zyss, J ;
Blanchard-Desce, M ;
Vaultier, M .
CHEMICAL COMMUNICATIONS, 2003, (22) :2766-2767
[3]  
[Anonymous], 1997, Nonlinear optics of organic molecules and polymers
[4]   Oxalate and 2,2′-bipyrimidine as bis-chelating ligands in the honeycomb layered compound {[Fe2(bpym)(ox)2]•5H2O}n [J].
Armentano, D ;
de Munno, G ;
Lloret, F ;
Julve, M ;
Curély, J ;
Babb, AM ;
Lu, JY .
NEW JOURNAL OF CHEMISTRY, 2003, 27 (01) :161-165
[5]   Inorganic arrays via multicomponent self-assembly: The spontaneous generation of ladder architectures [J].
Baxter, PNW ;
Hanan, GS ;
Lehn, JM .
CHEMICAL COMMUNICATIONS, 1996, (17) :2019-2020
[6]  
Benkstein KD, 2002, EUR J INORG CHEM, P2818
[7]   New non-dipolar structures with significant quadratic hyperpolarizabilities [J].
Blanchard-Desce, M ;
Baudin, JB ;
Ruel, O ;
Jullien, L ;
Brasselet, S ;
Zyss, J .
OPTICAL MATERIALS, 1998, 9 (1-4) :276-279
[8]   Towards highly efficient nonlinear optical chromophores: molecular engineering of octupolar molecules [J].
Blanchard-Desce, M ;
Baudin, JB ;
Jullien, L ;
Lorne, R ;
Ruel, O ;
Brasselet, S ;
Zyss, J .
OPTICAL MATERIALS, 1999, 12 (2-3) :333-338
[9]   Synthesis and molecular hyperpolarisabilities of donor-acceptor bipyridyl metal complexes (M = Re, Zn, Hg) [J].
Bourgault, M ;
Baum, K ;
Le Bozec, H ;
Pucetti, G ;
Ledoux, I ;
Zyss, J .
NEW JOURNAL OF CHEMISTRY, 1998, 22 (05) :517-522
[10]   Tetra(4-methoxyphenyl)phosphonium iodide: A twinned crystal built up with three-dimensional octupolar nonlinear optical chromophores [J].
Bourgogne, C ;
Le Fur, Y ;
Juen, P ;
Masson, P ;
Nicoud, JF ;
Masse, R .
CHEMISTRY OF MATERIALS, 2000, 12 (04) :1025-1033
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