A new class of bipyrimidine-based octupolar chromophores: synthesis, fluorescent and quadratic nonlinear optical properties

被引:46
作者
Akdas-Kilig, Huriye [1 ]
Roisnel, Thierry [1 ]
Ledoux, Isabelle [2 ]
Le Bozec, Hubert [1 ]
机构
[1] Univ Rennes 1, CNRS, UMR 6226, F-35042 Rennes, France
[2] ENS Cachan, Inst Alembert, CNRS, Lab Photon Quant & Mol,UMR 8537, F-94235 Cachan, France
关键词
CHARGE-TRANSFER; 2ND-ORDER POLARIZABILITY; 1ST HYPERPOLARIZABILITY; NONDIPOLAR STRUCTURES; THREEFOLD SYMMETRY; HIGHLY EFFICIENT; MOLECULES; COMPLEXES; CRYSTAL; DERIVATIVES;
D O I
10.1039/b907323j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
New D-2d octupolar organic chromophores based on bipyrimidine as a strong acceptor group exhibit strong fluorescence, fluorosolvatochromism and large second-order nonlinear optical responses.
引用
收藏
页码:1470 / 1473
页数:4
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