A Step Closer to the Electrochemical Production of Liquid Fuels

被引：61

作者：

Schouten, Klaas Jan P. ^{[1
,2
]}

Calle-Vallejo, Federico ^{[1
,3
]}

Koper, Marc T. M. ^{[1
]}

机构：

[1] Leiden Univ, Leiden Inst Chem, NL-2300 RA Leiden, Netherlands

[2] Avantium Chem, NL-1014 BV Amsterdam, Netherlands

[3] Univ Lyon, CNRS, ENS Lyon, Lab Chim, F-69364 Lyon 07, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2014年 / 53卷 / 41期

关键词：

CO reduction; copper catalysts; electrocatalysis; ethanol synthesis; sustainable energy; CARBON;

D O I：

10.1002/anie.201406174

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fueled by success: A nanostructured copper electrocatalyst derived from copper oxide can reduce carbon monoxide to multicarbon oxygenates including ethanol. This is an important step in the production of liquid fuel by the reduction of CO2 using electricity from renewable sources. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA Weinheim.

引用

页码：10858 / 10860

页数：3

共 11 条

[1]

Armaroli Nicola., 2011, Energy for a Sustainable World: From the Oil Age to a Sun-Powered Future

[2]

Calle-Vallejo F., 2013, ANGEW CHEM, V125, P7423, DOI [DOI 10.1002/ange.201301470, DOI 10.1002/ANGE.201301470]

[3]

Hori Y, 2008, MOD ASP ELECTROCHEM, P89

[4] Role of strain and ligand effects in the modification of the electronic and chemical properties of bimetallic surfaces [J].

Kitchin, JR ;

Norskov, JK ;

Barteau, MA ;

Chen, JG .

PHYSICAL REVIEW LETTERS, 2004, 93 (15) :156801-1

[5] Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper [J].

Li, Christina W. ;

Ciston, Jim ;

Kanan, Matthew W. .

NATURE, 2014, 508 (7497) :504-+

[6]

Liska AJ, 2014, NAT CLIM CHANGE, V4, P398, DOI [10.1038/nclimate2187, 10.1038/NCLIMATE2187]

[7] Effect of strain on the reactivity of metal surfaces [J].

Mavrikakis, M ;

Hammer, B ;

Norskov, JK .

PHYSICAL REVIEW LETTERS, 1998, 81 (13) :2819-2822

[8]

Parkinson B, 2013, RSC ENERGY ENVIRON S, P1

[9] Two Pathways for the Formation of Ethylene in CO Reduction on Single-Crystal Copper Electrodes [J].

Schouten, Klaas Jan P. ;

Qin, Zisheng ;

Gallent, Elena Perez ;

Koper, Marc T. M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (24) :9864-9867

[10] Is There a Road Ahead For Cellulosic Ethanol? [J].

Service, Robert F. .

SCIENCE, 2010, 329 (5993) :784-785

← 1 2 →